Home

Research

Dr. Balch

Members

 


 

Alan L. Balch

Department of Chemistry

 

Publications

 

2002

White-Morris, R. L., Olmstead, M. M., Jiang, F., and Balch, A. L.

New Insights into the Effects of Self-Association of the Cation [Au{C(NHMe)2}2]+ on Its Solid State Structure and Luminescence.

Inorg. Chem., 41, 2313-2315.    

Olmstead, M. M., de Bettencourt-Dias, A., Stevenson, S., Dorn, H. C., and Balch, A. L.

Crystallographic Characterization of the Structure of the Endohedral Fullerene {Er2@C82 Isomer I} with Cs Cage Symmetry and Multiple Sites for Erbium along a Band of Ten Contiguous Hexagons.

J. Am. Chem. Soc., 124, 4172-4173.    

Lee, H. M., Olmstead, M. M., Iezzi, E., Duchamp, J. C., Dorn, H. C., and Balch, A. L.

Crystallographic Characterization and Structural Analysis of the First Organic Functionalization Product of the Endohedral Fullerene SC3N@C80.

J. Am. Chem. Soc., 124, 3494-3495.    

White-Morris, R. L., Olmstead, M. M., Jiang, F., Tinti, D. S., and Balch, A. L.

Remarkable Variations in the Luminescence of Frozen Solutions of [Au{C(NHMe)2}2](PF6) 0.5(Acetone).  Structural and Spectroscopic Studies of the Effects of Anions and Solvents on Gold(I) Carbene Complexes.

J. Am. Chem. Soc., 124, 2327-2336.    

Lord, P. A., Latos-Grazynski, L. and Balch, A. L.

Reactivity of Iron Verdohemes with Phenylmagnesium Bromide.  Formation of Paramagnetic Iron-Phenyl Complexes.

Inorg. Chem., 41, 1011-1014.    

Kalish, H., Camp, J. E., Stepien, M., Latos-Grazynski, L., Olmstead, M. M., and Balch, A. L.

meso Substituent Effects on the Geometric and Electronic Structures of High-Spin and Low-Spin Iron(III) Complexes of Mono-meso-Substituted Octaethylporphyrins.

Inorg. Chem., 41, 989-997.    

Iezzi, E. B., Duchamp, J. C., Harich, K., Glass, T. E., Lee, H. M., Olmstead, M. M., Balch, A. L., and Dorn, H. C.

A Symmetric Derivative of the Trimetallic Nitride Endohedral Metallofullerene, Sc3N@C80.

J. Am. Chem. Soc., 124, 524-525.    

2001

Kalish, H., Camp, J. E., Stepien, M., Latos-Grazynski, L., and Balch, A. L.

Reactivity of Mono-Meso-Substituted Iron(II) Octaethylporphyrin Complexes with Hydrogen Peroxide in the Absence of Dioxygen.  Evidence for Nucleophilic Attack on the Heme.

J. Am. Chem. Soc., 123, 11719-11727.    

Lord, P. A., Noll, B. C., Olmstead, M. M., and Balch, A. L.

A Remarkable Skeletal Rearrangement of a Coordinated Tetrapyrrole:  Chemical Consequences of Palladium p-Coordination to a Bilindione.

J. Am. Chem. Soc., 123, 10554-10559.    

Johnson, J. A., Olmstead, M. M., Stolzenberg, A. M., and Balch, A. L.

Ring-Opening and Meso Substitution from the Reaction of Cyanide Ion with Zinc Verdohemes.

Inorg. Chem., 40, 5585-5595.    

Miller, G. P., Tetreau, M. C. , Olmstead, M. M., Lord, P. A., and Balch, A. L.

Addition of diprotic nucleophiles to a C60-tetrazine monoadduct:  structural reassignment and correction of a novel rearrangement.

Chem. Commun., 1758-1759.    

Latos-Grazynski, L., Wojaczynski, J., Koerner, R., Johnson, J. J., and Balch, A. L.

Verdoheme Reactivity.  Remarkable Paramagnetically Shifted 1H NMR Spectra of Intermediates from the Addition of Hydroxide or Methoxide with FeII and FeIII Verdohemes.

Inorg. Chem., 40, 4971-4977.    

Wang, J., Li, Y., Ma, D., Kalish, H., Balch, A. L., and La Mar, G. N.

Solution NMR Determination of the Seating(s) of Meso-nitro-etioheme-1 in Myoglobin:  Implications for Steric Constraints to Meso Position Access in Heme Degradation by Coupled Oxidation.

J. Am. Chem. Soc., 123, 8080-8088.    

Phillips, S., Noll, B. C., Olmstead, M. M., and Balch, A. L.

Oxidation of copper(II) hydroxyporphyrin (oxophlorin) oxidative ring opening and formation of an ester-linked, dinuclear copper complex.

Can. J. Chem., 79, 922-929.    

Olmstead, M. M., Jiang, F., Attar, S., and Balch, A. L.

Alteration of the Aurophilic Interactions in Trimeric Gold(I) Compounds through Charge Transfer.  Behavior of Solvoluminescent Au3(MeN=COMe)3 in the Presence of Electron Acceptors.

J. Am. Chem. Soc., 123, 3260-3267.    

Olmstead, M. M., de Bettencourt-Dias, A., Duchamp, J. C., Stevenson, S., Marciu, D., Dorn, H. C., and Balch, A. L.

Isolation and Structural Characterization of the Endohedral Fullerene Sc3N@C78.

Angew. Chemie Int. Ed., 40, 1223-1225.    

Satcher, Jr., J. H., Droege, M. W., Olmstead, M. M., and Balch, A. L.

A Mixed Oxidation State, Binuclear Iron Complex Containing an Unsymmetrically Coordinating Ligand.  A Ligand-Induced Switch in Redox Behavior.

Inorg. Chem., 40, 1454-1458.    

Dragoe, N., Shimotani, H., Wang, J., Iwaya, M., de Bettencourt-Dias, A., Balch, A. L., and Kitazawa.

First Unsymmetrical Bisfullerene, C121:  Evidence for the Presence of Both Homofullerene and Methanofullerene Cages in One Molecule.

J. Am. Chem. Soc., 123, 1294-1301.    

2000

Balch, A. L.

Structural Inorganic Chemistry of Fullerenes and Fullerene-Like Compounds

Fullerenes:  Chemistry, Physics, and Technology, K. M. Kadish and R. S. Rouff, editors, John Wiley & Sons, Inc., New York, Chap. 4, 177-223.

Kalish, H. R., Latos-Grazynski, L., and Balch, A. L.

Heme/Hydrogen Peroxide Reactivity:  Formation of Paramagnetic Iron Oxophlorin Isomers by Treatment of Iron Porphyrins with Hydrogen Peroxide.

J. Am. Chem. Soc., 122, 12478-12486.    

Olmstead, M. M., de Bettencourt-Dias, A., Duchamp, J. C., Stevenson, S., Dorn, H. C., and Balch, A. L.

Isolation and Crystallographic Characterization of ErSc2N@C80:  an Endohedral Fullerene Which Crystallizes with Remarkable Internal Order.

J. Am. Chem. Soc., 122, 12220-12226.    

Jiang, F., Olmstead, M. M. and Balch, A. L.

Aurophilic attractions:  one cation, [Au{C(OMe)NMeH}2]+, but three different structural arrangements in the solid state salts.

J. Chem. Soc., Dalton Trans., 4098-4103.    

Tran, A.-T. T., Kalish, H., Balch, A. L., and La Mar, G. N.

Solution 1H NMR investigation of the seating and rotational "hopping" of centrosymmetric etioheme-I in myoglobin:  effect of globin origin and its oxidation/spin state on heme dynamics.

J. Biol. Inorg. Chem., 5, 624-633.    

Olmstead, M. M., Wei, P.-P., Ginwalla, A. S., and Balch, A. L.

Bis(benzonitrile)palladium(II) Dihalides:  Structures and Cocrystallization of the Cubic Cluster Pd6Cl12 with (E)-Stilbene and with Bis(benzonitrile)palladium(II) Dichloride.

Inorg. Chem., 39, 4555-4559.    

Balch, A. L.

Coordination chemistry with meso-hydroxylated porphyrins (oxophlorins), intermediates in heme degradation.

Coordination Chemistry Reviews, 200-202, 349-377.    

Winkler, K., Noworyta, K., Kutner, W., and Balch. A. L.

Study of redox active C60/Pd films by simultaneous cyclic voltammetry and piezoelectric microgravimetry at an electrochemical quartz crystal microbalance.

Journal of the Electrochemical Society, 147, 2597-2603.    

Winkler, K., de Bettencourt-Dias, A., and Balch, A. L.

Electrochemical Studies of C60/Pd Films Formed by the Reduction of C60 in the Presence of Palladium(II) Acetate Trimer.  Effects of Varying C60/Pd(II) Ratios in the Precursor Solutions.

Chem. Mater., 12, 1386-1392.    

Dragoe, N., Shimotani, H., Hayashi, M., Saigo, K., de Bettencourt-Dias, A., Balch, A. L., Miyake, Y., Achiba, Y., and Kitazawa, K.

Electronic Interactions in a New Fullerene Dimer:  C122H4, with Two Methylene Bridges.

J. Org. Chem., 65, 3269-3273.    

Lee, J. W., Olmstead, M. M., Vickery, J. S., and Balch, A. L.

A Dumbbell Shaped Fullerene Dimer with An Inorganic Linker.  Addition of C60 and Tetracyanoethylene to Ir2(CO)2Cl2(Ph2P(CH2)nPPh2)2 (n = 5 or 7)*.

Journal of Cluster Science, 11, 67-77.    

Lord, P. A., Olmstead, M. M., and Balch, A. L.

Redox Characteristics of Nickel and Palladium Complexes of the Open-Chair Tetrapyrrole Octaethylbilindione:  A Biliverdin Model.

Inorg. Chem., 39, 1128-1134.    

Olmstead, M. M., Jiang, F. and Balch, A. L.

2C60 3CS2:  orientational ordering accompanies the reversible phase transition at 168 K.

Chem. Commun., 483-484.    

Winkler, K., Costa, D. A., and Balch, A. L.

Electrochemical Properties of Fullerene Based Solid Thin Layers.

Polish J. Chem., 74, 1-37.    

1999

Johnson, J. J., Olmstead, M. M., and Balch, A. L.

Reactivity of the Verdoheme Analogues.  Opening of the Planar Macrocycle by Amide and Thiolate Nucleophiles To Form Helical Complexes.

Inorg. Chem., 38, 5379-5383.    

Olmstead, M. M., Wei, P.-P., and Balch, A. L.

Solid-State Architectures of Aggregates of the Cubic Cluster [Pd6Cl12] with Polynuclear Aromatic Hydrocarbons.

Chem. Eur. J., 5, 3136-3142.    

Lord, P., Olmstead, M. M., and Balch, A. L.

Tetrapyrroles as p Donors:  A Pd22+ Unit Sandwiched between Two Helical Bilindione-Palladium Moieties.

Angew. Chem. Int. Ed., 38, 2761-2763.    

Stevenson, S., Rice, G., Glass, T., Harich, K., Cromer, F., Jordan, M. R., Craft, J., Hadju, E., Bible, R., Olmstead, M. M., Maitra, K., Fisher, A. J., Balch, A. L., and Dorn, H. C.

Small-bandgap endohedral metallofullerenes in high yield and purity.

Nature, 401, 55-57.    

Winkler, K., de Bettencourt-Dias, A., and Balch. A. L.

Charging Processes in Electroactive C60/Pd Films:  Effect of Solvent and Supporting Electrolyte.

Chem. Mater., 11, 2265-2273.    

Balch, A. L., Olmstead, M. M., and Vickery, J. C.

Gold(I) Compounds without Significant Aurophilic Intermolecular Interactions:  Synthesis, Structure, and Electronic Properties of Ph3PAuC(O)NHMe and Au3(PhCH2N=COMe)3:  Comparative Monomeric and Trimeric Analogues of the Solvoluminescent Trimer, Au3(MeN=COMe)3.

Inorg. Chem., 38, 3494-3499.    

Olmstead, M. M., Costa, D. A., Maitra, K., Noll, B. C., Phillips, S. L., Van Calcar, P. M., and Balch, A. L.

Interaction of Curved and Flat Molecular Surfaces.  The Structures of Crystalline Compounds Composed of Fullerene (C60, C60O, C70, and C120O) and Metal Octaethylporphyrin Units.

J. Am. Chem. Soc., 121, 7090-7097.    

Koerner, R., Olmstead, M. M., Ozarowski, A., and Balch, A. L.

A Linear Tetrapyrrole as a Binucleating Ligand with Copper(II).  Coordination beyond the Usual M-N4 Bonding.

Inorg. Chem., 38, 3262-3263.    

Wojaczynski, J., Latos-Grazynski, L., Chmielewski, P. J., Van Calcar, P., and Balch, A. L.

1H NMR Investigations of Triphenylporphyrin Metal Complexes and Electronic Interactions in Iron(III) Complexes of meso-meso-Linked 5,5'-Bis(10,15,20-triphenylporphyrin).

Inorg. Chem., 38, 3040-3050.    

Balch, A. L. and Olmstead, M. M.

Structural chemistry of supramolecular assemblies that place flat molecular surfaces around the curved exteriors of fullerenes.

Coord. Chem. Rev., 185-186, 601-617.    

Olmstead, M. M., Hao, L. and Balch A. L.

Organometallic C70 chemistry.  Preparation and crystallographic studies of (h2-C70)Pd(PPh3)2.CH2Cl2 and (C70).2{(h5-C5H5)2Fe}.

J. Organomet. Chem., 578, 85-90.    

Poblet, J. M., Winkler, K., Cancilla, M., Hayashi, A., Lebrilla, C. B., and Balch, A. L.

Geometric and Electronic Structure of Metal-Cage Fullerenes, C59M (M = Pt, Ir) Obtained by Laser Ablation of Electrochemically Deposited Films.

Chem. Comm., 493-494.    

St. Claire, T. N. and Balch, A. L.

In Situ Monitoring of the Degradation of Iron Porphyrins by Dioxygen with Hydrazine as Sacrifical Reductant.  Detection of Paramagnetic Intermediates in the Coupled Oxidation Process by 1H NMR Spectroscopy.

Inorg. Chem., 38, 684-691.    

Olmstead, M. M., Maitra, K. and Balch, A. L.

Formation of a Curved Silver Nitrate Network That Conforms to the Shape of C60 and Encapsulates the Fullerene-Structural Characterization of C60{Ag(NO3)}5.

Angew. Chem. Int. Ed., 38, 231-233.    

1998

Satcher, Jr., J. H., Olmstead, M. M., Droege, M. W., Parkin, S. R., Noll, B. C., May, L., and Balch, A. L.

Novel Square Arrangements in Tetranuclear and Octanuclear Iron(III) Complexes with Asymmetric Iron Environments Created by the Unsymmetric Bridging Ligand N,N,N'-Tris((N-methyl)-2-benzimidazolylmethyl)-N'-methyl-1,3-diamino-2-propanol.

Inorg. Chem., 37, 6751-6758.    

Winkler, K., Mojsa, R., Costa, D. A., and Balch, A. L.

Electrode Processes in a Thin Layer of Organic Solvent Covering a Hanging Mercury Drop Electrode.  Effects on Metal Ion and Fullerene (C60) Reduction.

Anal. Chem., 70, 5244-5251.    

Ecken, H., Olmstead, M. M., Noll, B. C., Attar, S., Schlyer, B., and Balch, A. L.

Effects of anions on the solid state structures of linear gold(I) complexes of the type (o-xylyl isocyanide)gold(I) (monoanion).

J. Chem. Soc., Dalton Trans., 3715-3720.    

Winkler, K., Costa, D. A., Balch, A. L., and Fawcett, W. R.

The electroreduction of C60 films in solutions containing crown ether complexes of alkali metal cations.

J. Electroanal. Chem., 456, 229-237.    

Winkler, K., Costa, D. A., Hayashi, A., and Balch, A. L.

Electrode Modification from the Electrolysis of [M(Bipyridine)3](ClO4)2 (M = CoII, FeII, and RuII) in Media of Low Dielectric Constant.  Electrocatalytic Behavior and an Amperometric C60 Sensor.

J. Phys. Chem. B, 102, 9640-9646.    

Balch, A. L. and Olmstead, M. M.

Reactions of Transition Metal Complexes with Fullerenes (C60, C70, etc.) and Related Materials.

Chem. Rev., 98, 2123-2165.    

Balch, A. L., Costa, D. A. and Winkler, K.

Formation of Redox-Active, Two-Component Films by Electrochemical Reduction of C60 and Transition Metal Complexes.

J. Am. Chem. Soc., 120, 9614-9620.    

Koerner, R., Latos-Grazynski, L. and Balch, A. L.

Models for Verdoheme Hydrolysis.  Paramagnetic Products from the Ring Opening of Verdohemes, 5-Oxaporphyrin Complexes of Iron(II), with Methoxide Ion.

J. Am. Chem. Soc., 120, 9246-9255.    

Latos-Grazynski, L., Johnson, J., Attar, S., Olmstead, M. M., and Balch, A. L.

Reactivity of the Verdoheme Analogues, 5-Oxaporhyrin Complexes of Cobalt(II) and Zinc(II), with Nucleophiles:  Opening of the Planar Macrocycle by Alkoxide Addition To Form Helical Complexes.

Inorg. Chem., 37, 4493-4499.    

Fung, E. Y., Olmstead, M. M., Vickery, J. C., and Balch, A. L.

Glowing gold rings:  solvoluminescence from planar trigold(I) complexes.

Coordination Chemistry Reviews, 171, 151-159.    

Attar, S., Forkey, D. M., Olmstead, M. M., and Balch, A. L.

Crystallographic characterization of the helical diketone, C36H14O2, a new product from the flash vacuum pyrolysis of decacyclene in the presence of oxygen.

Chem. Commun., 1255-1256.    

Balch, A. L.

Formation of Bonds among Other Second and Third Row Group VIII Metals in the Absence of Acid Ligands.

Book Chapter for Inorganic Reactions and Methods.  J. J. Zuckerman, Managing editor.  Wiley-VCH, New York, 91-99.    

Van Calcar, P. M., Olmstead, M. M., and Balch, A. L.

Ligand Connected Metal Clusters.  The Molecular Structures and Solid State Packing of {Ru3(CO)11}2(bis(diphenylphosphino)ethane) and {Ru3(CO)11}2(1,4-bis(diphenylphosphino)benzene).

Inorganica Chimica Acta, 270, 28-33.    

Koerner, R., Olmstead, M. M., Van Calcar, P. M., Winkler, K., and Balch, A. L.

Carbon Monoxide Production during the Oxygenation of Cobalt Complexes of Linear Tetrapyrroles.  Formation and Characterization of CoII(tetraethylpropentdyopent anion)2.

Inorg. Chem., 37, 982-988.    

Koerner, R., Olmstead, M. M., Ozarowski, A., Phillips, S. L., Van Calcar, P. M., Winkler, K., and Balch, A. L.

Possible Intermediates in Biological Metalloporphyrin Oxidative Degradation.  Nickel, Copper, and Cobalt Complexes of Octaethylformybiliverdin and Their Conversion to a Verdoheme.

J. Am. Chem. Soc., 120, 1274-1284.    

1997

Penn, S. G., Costa, D. A., Balch, A. L., and Lebrilla, C. B.

Analysis of C60 Oxides and C120On (n = 1,2,3) Using Matrix Assisted Laser Desorption-Ionization Fourier Transform Mass Spectrometry.

International Journal of Mass Spectrometry and Ion Processes, 169/170, 371-386.    

Balch, A. L., Catalano, V. J., Costa, D. A., Fawcett, W. R., Federco, M., Ginwalla, A. S., Lee, J. W., Olmstead, M. M., Noll, B. C., and Winkler, K.

Transition Metal Fullerene Chemistry:  The Route from Structural Studies of Exohedral Adducts to the Formation of Redox Active Films.

J. Phys. Chem. Solids, 58, 1633-1643.    

Vickery, J. C. and Balch, A. L.

X-ray Crystallographic Studies of the Products of Oxidative Additions of Iodine to Cyclic Trinuclear Au(I) Complexes:  Directional Effects for Au-II-Au Interactions.

Inorganic Chemistry, 36, 5978-5983.    

Arasasingham, R. D., Balch, A. L., Olmstead, M. M., and Phillips, S. L.

Paramagnetic iron(III) and diamagnetic gallium(III) porphyrin complexes with axial allyl and vinyl ligands.

Inorganica Chimica Acta, 263, 161-170.    

Van Calcar, P. M., Olmstead, M. M., and Balch, A. L.

Architecture of Crystalline Polymers Formed from the Binuclear Complexes XAuPh2P(CH2)nPPh2AuX through Weak Au(I)Au(I) Interactions.

Inorg. Chem., 36, 5231-5238.    

Wojaczynski, J., Latos-Grazynski, L., Olmstead, M. M., and Balch, A. L.

Cyclic Metalloporphyrin Trimers:  1H NMR Identification of Trimeric Heterometallic (Iron(III), Gallium(III), Manganese(III)) 2-Hydroxy-5,10,15,20-tetraphenylporphyrins and X-ray Crystal Structure of the Iron(III) 2-Hydroxy-5,10,15,20-tetra-p-tolylporphyrin Trimer.

Inorg. Chem., 36, 4548-4554.    

Balch, A. L., Koerner, R., Latos-Grazynski, L., Lewis, J. E., St. Claire, T. N., and Zovinka, E. P.

Coupled Oxidation of Heme without Pyridine.  Formation of Cyano Complexes of Iron Oxophlorin and 5-Oxaporphyrin (Verdoheme) from Octaethylheme.

Inorg. Chem., 36, 3892-3897.    

Vickery, J. C., Olmstead, M. M., Fung, E. Y., and Balch, A. L.

Solvent-Stimulated Luminescence from the Supramolecular Aggregation of a Trinuclear Gold(I) Complex that Displays Extensive Intermolecular AuAu Interactions.

Angew. Chem. Int. Ed. Engl., 36, 1179-1181.    

Forkey, D. M., Attar, S., Noll, B. C., Koerner, R., Olmstead, M. M., and Balch, A. L.

Crystallographic Characterization of the Molecular Structure and Solid State Packing of the Fullerene-Shaped Hydrocarbon C36H12.

J. Am. Chem. Soc., 119, 5766-5767.    

Attar, S., Ozarowski, A., Van Calcar, P. M., Winkler, K., and Balch, A. L.

Axial ligation modulates the electron distribution in helical cobalt complexes derived from octaethylbinindione.

Chem. Commun., 1115-1116.    

Balch, A. L., Costa, D. A., Fawcett, W. R., and Winkler, K.

The solvent effect on the electrochemical behavior of C60 films in the presence of alkali-metal cations.

Journal of Electroanalytical Chemistry, 427, 137-146.    

Winkler, K., Costa, D. A., Fawcett, W. R., and Balch, A. L.

Alteration of the Electrochemistry of Fullerene C60 in the Presence of Dioxygen:  Formation of a Redox-Active Polymeric Film.

Adv. Mater., 9, 153-156.    

Attar, S., Balch, A. L., Van Calcar, P. M., and Winkler, K.

Electron Transfer Behavior and Solid State Structures of the Helical Cobalt Complexes of the Open-Chain Tetrapyrrole Ligand, Octaethylbilindione.

J. Am. Chem. Soc., 119, 3317-3323.    

Chmielewski, P. J., Latos-Grazynski, L., Olmstead, M. M. and Balch, A. L.

Nickel Complexes of 21-Oxaporphyrin and 21,23-Dioxaporphyrin.

Chem. Eur. J., 3(2), 268-278.    

Ginwalla, A. S., Balch, A. L. and Kauzlarich, S. M.

Synthesis and Characterization of the Europium Fullerides EuxC60 (x = 1-6).

Chem. Mater., 9, 278-284.    

1996

Van Calcar, P. M., Olmstead, M. M. and Balch, A. L.

Self-assembly of metal complexes with cyclophane or polymeric chain structures about a 1,3,5-tris(diphenylphosphino)benzene core.

Chem. Commun., 2597-2598.    

Balch, A. L., Noll, B. C., Olmstead, M. M., and Phillips, S. L.

Structural and Spectroscopic Characterization of Iron(III) Dioxoporphodimethene Complexes and Their Autoreduction to an Iron(II) Complex in Pyridine.

Inorg. Chem., 35, 6495-6506.    

Balch, A. L., Costa, D. A. and Olmstead, M. M.

Structural characterization of C70O.    Remarkable disorder in crystalline  [(h2-C70O)Ir(CO)Cl(PPh3)2] 5C6H6.

Chem. Commun., 2449-2450.    

Olmstead, M. M., Ginwalla, A. S., Noll, B. C., Tinti, D. S., and Balch, A. L.

Supramolecular Aggregation of Pd6Cl12, a Cluster of Comparable Size to a Fullerene, with Aromatic Donors and with C60.

J. Am. Chem. Soc., 118(33), 7737-7745.    

Balch, A. L., Hao, L., and Olmstead, M. M.

Patterns of Multiple Additions to Fullerene C70:  Isolation and Structural Characterization of [C70{Pt(PPh3)2}4].

Angew. Chem. Int. Ed. Engl., 35(2), 188-190.    

Weissbart, B., Toronto, D. V., Balch, A. L., and Tinti, D. S.

Optical and ODMR Studies of Luminescent Halo(dimethylphenyl-phosphine)gold(I) Crystals.

Inorg. Chem., 35, 2490-2496.    

Toronto, D. V., Weissbart, B., Tinti, D. S., and Balch, A. L.

Solid State Structures and Gold-Gold Bonding in Luminescent Halo(dimethylphenylphosphine)gold(I) Complexes.

Inorg. Chem., 35, 2484-2489.    

Balch, A. L., Costa, D. A., Fawcett, W. R., and Winkler, K.

Electronic Communication in Fullerene Dimers.  Electrochemical and Electron Paramagnetic Resonance Study of the Reduction of C120O.

J. Phys. Chem., 100(12), 4823-4827.    

Balch, A. L., Ginwalla, A. S., Olmstead, M. M., and Herbst-Irmer, R.

Structural Analysis of Products from the C60-Piperazine Reaction.  Consistent Geometric Distortions of the Fullerene Core Upon Adduct Formation.

Tetrahedron, 52(14), 5021-5032.    

Satcher, Jr., J. H., Balch, A. L., Olmstead, M. M., and Droege, M. W.

An Unsymmetrical, Doubly Bridged Diiron(II) Complex with Readily Accessible Coordination Sites.

Inorg. Chem., 35, 1749-1750.    

Balch, A. L., Koerner, R., Latos-Grazynski, L., and Noll, B. C.

A Role for Electron Transfer in Heme Catabolism?  Structure and Redox Behavior of an Intermediate, (Pyridine)2Fe(octaethyloxophlorin).

J. Am. Chem. Soc., 118(11), 2760-2761.    

Latos-Grazynski, L., Pacholska, E., Chmielewski, P.J., Olmstead, M.M., and Balch, A.L.

5,20-Diphenyl-10,15-bis(p-tolyl)-21-selenaporphyrin and Its Nickel(II) Complexes.

Inorg. Chem., 35, 566-573.    

Balch, A.L., Costa, D.A., Noll, B.C., and Olmstead, M.M.

Developing Reagents To Orient Fullerene Derivatives.  Formation and Structural Characterization of (h2-C60O)Ir(CO)Cl(As(C6H5)3)2.

Inorg. Chem., 35, 458-462.    

1995

Balch, A.L.

Reactions of Fullerenes with Inorganic and Organometallic Compounds.

"Advanced Series in Fullerenes, Vol. 4, The Chemistry of Fullerenes", Taylor, R. ed., World Scientific Publishing Co. Pte. Ltd., Singapore, 220-262.    

Latos-Grazynski, L., Pacholska, E., Chmielewski, P.J., Olmstead, M.M., and Balch, A.L.

Alteration of the Reactivity of a Tellurophene Within a Core-Modified Porphyrin Environment:  Synthesis and Oxidation of 21-Telluraporphyrin.

Angew. Chem. Int. Ed. Engl., 34(20), 2252-2254.    

Winkler, K., Costa, D.A., Balch, A.L., and Fawcett, W.R.

A Study of Fullerene Epoxide Electroreduction and Electropolymerization Processes.

J. Phys. Chem., 99, 17431-17436.    

Balch, A.L., Cullison, B., Fawcett, W.R., Ginwalla, A.S., Olmstead, M.M., and Winkler, K.

Structural and Electrochemical Characterization of the Products of the C60-Piperazine Reaction.

J. Chem. Soc., Chem. Commun., 2287-2288.    

Balch, A.L.

Construction of Ordered Solids and Polymers from Fullerene Components.

"Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials", Harrod, J.F., Laine, R.M. eds., Klewer Academic Publishers, Boston, MA, 283-301.    

Van Calcar, P.M., Olmstead, M.M., and Balch, A.L.

Construction of a Knitted Crystalline Polymer through the Use of Gold(I)-Gold(I) Interactions.

J. Chem. Soc., Chem. Commun., 1773-1774.    

Balch, A.L., Costa, D.A., Noll, B.C., and Olmstead, M.M.

Oxidation of Buckminsterfullerene with m-Chloroperoxybenzoic Acid.  Characterization of a Cs Isomer of the Diepoxide C60O2.

J. Am. Chem. Soc., 117, 8926-8932.    

Satcher, Jr., J.H. and Balch, A.L.

Magnetic Coupling and 1H NMR Spectroscopy of Binuclear Copper(II) Complexes.

Inorg. Chem., 34, 3371-3373.    

Balch, A.L., Koerner, R., and Olmstead, M.M.

Crystallographic Characterization of Octaethylverdohaem.

J. Chem. Soc., Chem. Commun., 873-874.    

Balch, A.L., Mazzanti, M., St. Claire, T. N., and Olmstead, M.M.

Production of Oxaporphyrin and Biliverdin Derivatives by Coupled Oxidation of Cobalt(II) Octaethylporphyrin.

Inorg. Chem., 34, 2194-2200.    

Balch, A.L., Koerner, R., Olmstead, M. M., Mazzanti, M., Safari, N., and St. Claire, T.

Solid-state Self-association of the Two-electron Oxidation Product of a Biliverdin Analogue.

J. Chem. Soc., Chem. Commun., 643-644.    

Balch, A.L., Latos-Grazynski, L., and St. Claire, T. N.

Chemistry of Iron Oxophlorins.3  Reversible, One-Electron Oxidation of Iron(III) Octaethyloxophlorin Dimer.

Inorg. Chem., 34, 1395-1401.    

Fedurco, M., Costa, D. A., Balch, A. L., and Fawcett, W. R.

Electrochemical Synthesis of a Redox-Active Polymer Based on Buckminsterfullerene Epoxide.

Angewandte Chemie, 34(2), 194-196.    

1994

Toronto, D.V. and Balch, A. L.

Formation of Trinuclear Complexes by Addition of Mercury(II) Halides and Gold(I) Halides to  Pt2(m-dpm)2(CN)2.

Inorg. Chem., 33, 6132-6139.    

Balch, A. L., Lee, J. W., Noll, B. C., and Olmstead, M. M.

A Crystalline Salt of (C60-):[(h5-C5H5)2Co+](C60-)•CS2.  Fullerenes.

Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials.  Edited by K. M. Kadish and R. S. Ruoff, Volume 94-24, 1231-1244.    

Balch, A. L., Lee, J. W., Noll, B. C., and Olmstead, M. M.

Multiple Additions of Vaska-Type Iridium Complexes to C60.  Preferential Crystallization of the "Para" Double Addition Products C60{Ir(CO)Cl(PMe3)2}2•2C6H6 and C60{Ir(CO)Cl(PEt3)2}2•C6H6.

Inorg. Chem., 33, 5238-5243.    

Balch, A. L., Mazzanti, M., Noll, B. C., and Olmstead, M. M.

Coordination Patterns for Biliverdin-Type Ligands.  Helical and Linked Helical Units in Four-Coordinate Cobalt and Five-Coordinate Manganese(III) Complexes of Octaethylbilindione.

J. Am. Chem. Soc., 116, 9114-9122.    

Bürgi, H. B., Restori, R., Schwarzenbach, D, Balch, A. L., Lee, J. W., Noll, B. C., and Olmstead, M. M.

Nanocrystalline Domains of a Monoclinic Modification of Benzene Stabilized in a Crystalline Matrix of C60.

Chem. Mater., 6, 1325-1329.    

Balch, A. L., Olmstead, M. M., Safari, N. and St. Claire, T. N.

Iron(III) Porphyrin Complexes with Axial Alkyl and Acyl Ligands.  Structures and Reactivity of the Acyl Complex toward Dioxygen.

Inorg. Chem., 33, 2815-2833.    

Toronto, D. V., Balch, A. L. and Tinti, D. S.

Photoluminescence from Electron-Deficient, Mixed-Metal Clusters with [Pt2Au]3+ and [Pt2Hg]4+ Cores.

Inorg. Chem., 33, 2507-2508.    

Balch, A. L., Costa, D. A., Lee, J. W., Noll, B. C. and Olmstead, M. M.

Directing Effects in a Fullerene Epoxide Addition.  Formation and Structural Characterization of (h2-C60O)Ir(CO)Cl(P(C6H5)3)2.

Inorg. Chem., 33, 2071-2072.    

Balch, A. L., Ginwalla, A. S., Lee, J. W., Noll, B. C. and Olmstead, M. M.

Partial Separation and Structural Characterization of C84 Isomers by Crystallization of (h2-C84)Ir(CO)Cl(P(C6H5)3)2.

J. Am. Chem. Soc., 116, 2227-2228.    

Balch, A. L., Mazzanti, M., and Olmstead, M. M.

Preparation of a Cobalt Analogue of Verdoheme by Coupled Oxidation of Cobalt(II) Octaethylporphyrin.

J. Chem. Soc., Chem. Commun., 269-270.    

Latos-Grazynski, L., Lisowski, J., Chmielewski, P., Grzeszczuk, M., Olmstead, M. M., and Balch, A. L.

Palladium Complexes of 21-Thiaporphyrin:  Syntheses and Characterization.

Inorganic Chemistry, 33, 192-197.    

1993

Balch, A. L., Mazzanti, M., Noll, B. C., and Olmstead, M. M.

Geometric and Electronic Structure and Dioxygen Sensitivity of the Copper Complex of Octaethylbilindione, a Biliverdin Analog.

J. Am. Chem. Soc., 115, 12206-12207.    

Balch, A. L., Latos-Grazynski, L., Noll, B. C., Szterenberg, L., and Zovinka, E. P.

Chemistry of Iron Oxophlorins.2  Oxidation of the Iron(III) Octaethyloxophlorin Dimer and Observation of Stepwise, Two-Electron Oxidation of the Oxophlorin Macrocycle.

J. Am. Chem. Soc., 115, 11846-11854.    

Balch, A.L.

Construction of Small Polynuclear Complexes with Trifunctional Phosphine-Based Ligands as Backbones.

Progress in Inorganic Chemistry, 41, 239-329. (In press last action.)    

Balch, A. L., Mazzanti, M., and Olmstead, M. M.

Cobalt Complexes of Octaethyloxophlorin.  Metal-Centered Redox Chemistry in the Presence of a Redox-Active Ligand.

Inorganic Chemistry, 32, 4737-4744. (In press last action.)    

Balch, A. L., Noll, B. C., Phillips, S. L., Reid, S. M., and Zovinka, E. P.

Nickel(II) Complexes of the Octaethyloxophlorin Dianion and Octaethyloxophlorin Radical Dianion.

Inorganic Chemistry, 32, 4730-4736. (In press last action.)    

Balch, A. L., Latos-Grazynski, L., Noll, B. C., Olmstead, M. M. and Safari, N.

Isolation and Characterization of an Iron Biliverdin-Type Complex That Is Formed along with Verdohemochrome during the Coupled Oxidation of Iron(II) Octaethylporphyrin.

Journal of the American Chemical Society, 115, 9056-9061. (In press last action.)    

Balch, A.L., Davis, B.J., and Olmstead, M.M.

Complexes with a Triflurophosphine Ligand Bridging a Tripalladium Triangle.  Structure of [Pd3(h3-PF3)(h3-I)(m-bis(diphenylphosphino)methane)3]I.

Inorganic Chemistry, 32, 3937-3942.    

Balch, A.L., Olmstead, M.M. and Phillips, S.L.

Identification of Isomeric meso-Dioxo Derivatives of Octaethylporphyrin and Separation and Structural Characterization of the Nickel(II) Complexes.

Inorganic Chemistry, 32, 3931-3936.    

Balch, A.L., Davis, B.J., Fung, E.Y. and Olmstead, M.M.

Palladium-Thallium Interactions in Dinuclear Complexes with Structural Components that Place the Two metal Centers in Close Proximity.

Inorganic Chimica Acta (Invited contribution), 212, 149-156.    

Balch, A.L., Noll, B.C., Olmstead, M.M. and Toronto, D.V.

Heterodinuclear Bis(diphenylphosphino)methane-Bridged Molybdenuim(d6)-Palladium(d8) Complexes with Dative Mo Ø Pd Bonding.

Inorganic Chemistry, 32, 3613-3619.    

Balch, A.L., Lee, J.W., Noll, B.C. and Olmstead, M.M.

Structural Characterization of {h2-C60)RhH(CO)(PPh3)2} The Product of the Reaction of C60 with the Hydrogenation Catalyst, {RhH(CO)(PPh3)3}.

Inorganic Chemistry, 32, 3577-3578.    

Balch, A.L., Fung, E.Y., Nagle, J.K., Olmstead, M.M., Rowley, S.P.

Lead(II)/Platinum(II) Complexes With and Without Pb-Pt Interactions.

Inorganic Chemistry, 32, 3295-3299.    

Balch, A.L., Noll, B.C., Olmstead, M.M. and Reid, S.M.

A Cofacial, Dimeric, Metallaoxophlorin Complex:  {InIII(Octaethyloxophlorin)}2.

J. Chem. Soc. Chem. Commun., 1088-1090.    

Balch, A.L., Noll, B.C. and Safari, N.

Structural Characterization of Low-Spin Iron (III) Complexes of Octaethyloxaporphyrin.

Inorganic Chemistry, 32, 2901-2905.    

Balch, A.L., Noll, B.C., Reid, S.M. and Zovinka, E.P.

Coordination Patterns for Oxophlorin Ligands.  Pyridine Induced Cleavage of Dimeric Manganese(III) and Iron(III) Octaethyloxophlorin Complexes.

Inorganic Chemistry, 32, 2610-2611.    

Weissbart, B., Balch, A. L. and Tinti, D. S.

Temperature and Magnetic Field Effects on the Luminescence of Tl2Pt(CN)4.

Inorganic Chemistry, 32, 2096-2103.    

Balch, A.L., Hart, R.L. and Parkin, S.

Axial Alkyl Ligand Reactivity in Five-Coordinate Gallium(III) Porphyrin Complexes.

Inorganica Chimica Acta, 205, 137-143.    

Balch, A.L., Noll, B.C., Reid, S.M. and Zovinka, E.P.

Carbon-Carbon Bond Formation in the Dimerization of Nickel(II)(octaethyloxophlorin radical).

Journal of the American Chemical Society, 115, 2531-2532.    

Balch, A.L., Latos-Grazynski, L., Noll, B.C. and Phillips, S.L.

Acetylide Complexes of Diamagnetic Gallium(III) and Paramagnetic Iron(III) Porphyrins.

Inorganic Chemistry, 32, 1124-1129.    

Balch, A.L., Latos-Grazynski, L., Noll, B.C., Olmstead, M.M., Szterenberg, L. and Safari, N.

Structural Characterization of Verdoheme Analogs.  Iron Complexes of Octaethyloxoporphyrin.

Journal of the American Chemical Society, 115, 1422-1429.    

Balch, A.L., Olmstead, M.M. and Safari, N.

Octaethylazaporphyrin iron(III) chloride:  Its Structure in the Solid State and in Solution.

Inorganic Chemistry, 32, 291-296.    

Balch, A.L., Lee, J.W., Noll, B.C. and Olmstead, M.M.

Disorder in a Crystalline Form of Buckministerfullerene:  C60•4C6H6.

J. Chem. Soc., Chem. Commun., 56-58.    

1992

Balch, A.L., Lee, J.W., Noll, B.C. and Olmstead, M.M.

A Double Addition Product of C60:  C60{Ir(CO)Cl(PMe2Ph)2}2.  Individual Crystallization of Two Conformational Isomers.

Journal of the American Chemical Society, 114, 10984-10985.    

Balch, A. L., Noll, B. C., Olmstead, M. M., and Toronto, D. V.

Heterodinuclear Bis(diphenylphosphino)methane-Briged Molybdenum (d6)-Gold (d10) Complexes: Metal-Metal Interactions and Ligand Oxidation.

Inorganic Chemistry, 31, 5226-5230.    

Balch, A.L., Lee, J.W. and Olmstead, M.M.

Isolation and Structural Characterization of a Product of Double Addition to C70:  C70{Ir(CO)Cl(PPhMe2)2}2•3C6H6.

Angewandte Chemie, 31, 1356-1358.    

Balch, A.L. and Catalano, V.J.

Structural Motifs in Dinuclear d8 Metal Complexes.  Structural and Spectroscopic Characteristics of an Alternative Unsymmetrical 3:5 Ligand Distribution As compared to the Symmetrical 4:4 or Face-to-Face Arrangement.

Inorganic Chemistry, 31, 3934-3942.    

Balch, A.L.

The Reactivity of Spectroscopically Detected Peroxy Complexes of Iron Porphyrins.

Inorganica Chimica Acta, 198-200, 297-307. ( Invited Contribution)    

Balch, A.L. and Catalano, V.J.

Reactivity of Complexes with Weak Metal-Metal Bonds.  Reactions of Lewis Acids with [AuIr(CO)Cu(µ-Ph2PCH2PPh2)2](PF6).

Inorganic Chemistry, 31, 2730-2734.    

Balch, A.L. and Catalano, V.J.

Formation of Luminescent, Metal-Metal Bonded, 3:5 Complexes Using Palladium(II) or Platinum(II) and Iridium(I) through Chelate Ring Openings,

Inorganic Chemistry, 31, 2569-2575.    

Balch, A.L., Catalano, V.J., Lee, J.W. and Olmstead, M.

Supramolecular Aggregation of an (h2-C60) Iridium Complex Involving Phenyl Chelation of the Fullerene.

Journal of the American Chemical Society, 114, 5455-5457.    

Balch, A.L., Latos-Grazynski, L., Noll, B.C., Olmstead, M.M. and Zovinka, E.P.

The Chemistry of Iron Oxophlorins, I.  1H NMR and Structural Studies of Five-Coordinate Iron(III) Complexes.

Inorganic Chemistry, 31, 2248-2255.    

Balch, A.L., Noll, B.C. and Zovinka, E.P.

Structural Characterization of Zinc(II) Complexes of Octaethyloxophlorin Dianion and Octaethyloxophlorin Radical Anion.

Journal of the American Chemical Society, 114, 3380-3385.    

Balch, A.L., Latos-Grazynski, L., Noll, B.C., Olmstead, M.M. and Zovinka, E.P.

Geometric and Electronic Structure of Paramagnetic Tetraarylporphyrin Complexes of Chromium.

Inorganic Chemistry, 31, 1148-1151.    

Balch, A.L., Cornman, C.R., Latos-Grazynski, L. and Renner, M.W.

Highly Oxidized Iron Complexes of N-Methyltetra(p-tolyl)porphyrin.

Journal of the American Chemical Society, 114, 2230-2237.    

1991

Balch, A.L., Catalano, V.J., Lee, J.W., Olmstead, M.M. and Parkin, S.R.

(h2-C70)Ir(CO)Cl(PPh3)2.  The Synthesis and Structure of an Organometallic Derivative of a Higher Fullerene.

Journal of the American Chemical Society.113, 8953.    

Guimerans, R.R., Noll, B.C., Olmstead, M.M., Balch, A.L.

Mercury(II) Complexes of Bis(diphenylphosphinomethyl)phenylphosphine.

Inorganica Chimica Acta, 187, 181-186    

Balch, A.L., Catalano, V.J. and Lee. J.W.

Accumulating Evidence for the Selective Reactivity of the 6-6 Ring Fusion of C60.  Preparation and Structure of (h2-C60)Ir(CO)Cl(PPh3)2•5C6H6.

Inorganic Chemistry, 30, 3980-3981    

Balch, A.L., Neve, F., Olmstead, M.M.

Assessing the Effects of Metal Ion Proximity on a trans-Ir(CO)Cl(phosphine)2 Unit.  Structural Studies of Potassium(I), Tin(II), and Lead(II) Complexes of (crown-P2)Ir(CO)Cl.

Inorganic Chemistry, 30, 3395.    

Keating, K.A., de Ropp, J.S., La Mar, G.N., Balch, A.L., Shiau, F.Y. and Smith, M.

Assignment by 2D NMR Bond Correlation Spectroscopy of Hyperfine-Shifted and Strongly Relaxed Protons in Iron Porphyrin and Chlorin Complexes.

Inorganic Chemistry, 30, 3258.    

Latos-Grazynski, L., Lisowski, J., Szterenberg, L. Olmstead, M. M., Balch A.L.

Crystal and Molecular Structure of 21-Thia-5,20-diphenyl-10,15-di-(p-nitrophenyl)porphyrin and 21,23-Dithiatetraphenylporphyrin.  The Influence of Sulfur on the p-Delocalization Pattern.

Journal of Organic Chemistry, 56, 4043.    

Balch, A.L., Neve, F. and Olmstead, M.M.

Studies of Thallium-Iridium Bonding.

Journal of the American Chemical Society, 113: 2995-3001    

Balch, A.L., Catalano, V.J., Ligation-Induced Changes in Metal-Metal

Bonding in Luminescent Binuclear Complexes Containing Gold(I) and Iridium(I).

Inorganic Chemistry, 30: 1302-1308    

Balch, A.L., V.J. Catalano, M.A. Chatifled, J.K. Nagle, M.M. Olmstead and P.E. Reedy, Jr.

Binding of Lead(II), Antimony(III) and Other Isoelectronic Main Group Ions to Iridium in the Metallomacrocycle Ir2(CO)2Cl2{m-(Ph2PCH2)2AsPh}2.

Journal of the American Chemical Society, 113: 1252-1258.    

1990

Balch, A.L., B.J. Davis and M.M. Olmstead.

Triply-Bridging Trifluorophosphine.  Formation of [h3-F3P)Pd3(Ph2PCH2PPh2)3(m-Cl)]+ by Disporportionation of Pd2(m-Ph2PCH2PPh2)2Cl2.

Journal of the American Chemical Society: 112. 8592-8593.    

Balch, A.L. and E.Y. Fung.

Two- and Four-Coordinate Gold(I) Complexes of Tris(3-diphenylphosphinoethyl)phosphine.

Inorganic Chemistry: 29, 4764-4771.    

Arasasingham, R.D., A. L. Balch, R.L. Hart and L. Latos-Grazynski.

Reactions of Aryl Iron(III) Porphyrins with Dioxygen.  Formation of Aryloxy Iron(III) and Aryl Iron(IV) Complexes.

Journal of the American Chemical Society:  112, 7566-7571.    

Balch, A.L., V. Catalano, B. Noll and M.M. Olmstead.

Reactions Involving Chelate Ring Opening or Metal Ion Relocation in the Formation of Luminescent Complexes Containing both Gold and Iridium.

Journal of the American Chemical Society: 112, 7558-7566.    

Balch, A. L., C. R. Cornman, L. Latos-Grazynski and M. M. Olmstead.

Characterizaiton of Five- and Six-Coordinate Iron(III) Complexes of N-Methylporphyrins.

Journal of the American Chemical Society:  112, 7552-7558.    

Balch, A.L.

Formation, Structure and Luminescent Properties of Metal-Metal Bonded Compounds of the Late Transition Metal and Post Transition Metal Ions.

"Metal-Metal Bonds and Clusters in Chemistry and Catalysis" (Fackler, J.P. Jr., ed.), Plenum Press, N.Y., 299-309.     

Balch, A.L., C.R. Cornman and N. Safari.

1H NMR Studies of the Reduction of Paramagnetic Iron(II) Alkyl Porphyrin Complexes to Diamagnetic Iron(II) Alkyl Complexes.

Organometallics: 9, 2420-2421.    

Balch, A.L., R. L. Hart, L. Latos-Grazynski and T. G. Traylor.

Nuclear Magnetic Resonance Studies of the Formation of Tertiary Alkyl Complexes of Iron(III) Porphyrins and their Reactions with Dioxygen.

Journal of the American Chemical Society: 112, 7382-7388.    

Balch, A.L., R.H. Hart and L. Latos-Grazynski.

Nuclear Magnetic Resonance Studies of Hydroquinone Dianion Bridged Iron(III) Porphyrin Dimers.

Inorganic Chemistry, Inorganic Chemistry: 29, 3523-3526.    

Balch, A.L., E.Y. Fung and M.M. Olmstead.

Preparation and Structure of Two Polynuclear Aggregates Obtained Using the Metalloligand {ClAuPPh2CH2}2AsPh.

Inorganic Chemistry: 29,3203-3207.    

Balch, A.L., B.J. Davis and M.M. Olmstead.

Metal Ions as Ligands: Complexation of Tin(II) Chloride by the Bidentate Ligand [Ir2(CO)2Cl2{Ph2P(CH2)4PPh}2].

Inorganic Chemistry: 29, 3066-3068.    

Balch, A.L. and S.P. Rowley.

Solubilizing the Tl-Pt Unit of Tl2Pt(CN)4.  Preparation and Use of a New Crown Ether/Phosphine Hybrid Ligand for Linking Main Group and Transition Metal Ions.

Journal of the American Chemical Society: 112, 6139-6140.    

Balch, A.L., E.Y. Fung and M.M. Olmstead.

Polynuclear (Diphenylphosphinomethyl)phenylarsine Bridged Complexes of Gold(I).  Bent Chains of Gold(I) and a Role for Au(I)-Au(I) Interactions in Guiding a Reaction .

Journal of the American Chemical Society, 112: 5181-5186.    

Arasasingham, R.D., A.L. Balch, C.R. Cornman, J.S. de Ropp, K. Eguchi and G.N. La Mar.

1H NMR Studies of Iron(III) Porphyrins with Axial Phenoxide or Thiophenoxide Ligands.

Inorganic Chemistry, 29:1847-1850.    

Balch, A.L., V.J. Catalano and M.M. Olmstead.

Structural Changes Accompanying Oxidative-Additions of Tetrachloro-1,2-benzoquinone to Phosphine-Bridged Bi- and Tri-Rhodium Complexes.

Inorganic Chemistry, 29: 1638-1642.    

Balch, A.L., V.J. Catalano and M.M. Olmstead.

Chelate Ring Opening and Metal Ion Relocation Leading to the Formation of a Luminescent AuIIrIAuI Chain Complex.

Journal of the American Chemical Society, 112: 2010-2011.    

Balch, A.L., M.M. Olmstead and S.P. Rowley.

Preparation and Structural Characterization of Rhodium and Palladium Complexes of Mixed Phosphine/Amine Ligands with Methylene Spacers between Donor Atoms.

Inorganica Chimica Acta, 168: 255-264.    

Balch, A.L., V.J. Catalano and M.M. Olmstead.

The Structure and Photoluminescence of a Heterodinuclear d10-d8 Complex, [AuIr(CO)Cl(m-Ph2PCH2PPh2)2][PF6].

Inorganic Chemistry, 29: 585-586.    

Balch, A.L., C.R. Cornman and M.M. Olmstead.

Formation and Structure of Alkylperoxide Complexes of Germanium(IV) Porphyrins from Direct Reactions with Alkylhydroperoxides and by Photolysis of Alkyl Germanium(IV) Porphyrins in the Presence of Dioxygen.

Journal of the American Chemical Society, 112: 2963-2969.    

1989

Guimerans, R.R., E. C. Hernandez, M.M. Olmstead and A.L. Balch.

Synthesis, Structure and Structural Dynamics of Ruthenium(II) Bis(2-diphenylphosphinoethyl)phenylphosphine Dichloride.

Inorganica Chimica Acta, 165: 45-50.    

Latos-Grazynski, L., A.L. Balch, and M.M. Olmstead.

The First Structural Characterization of a NiI Macrocyclic System: Structure of NiIDiphenyldi-p-tolyl-21-thiaporphyrin.

Inorganic Chemistry, 28:4065-4066.    

Arasasingham, R.D., C.R Cornman and A.L. Balch.

Detection of Hydroperoxo and Ferryl, (FeIV=O)2+, Intermediates During the Reaction of t-Butylhydroperoxide with Iron Porphyrins in Toluene Solution.

Journal of the American Chemical Society, 111:7800-7805.    

Latos-Grazynski, L., J. Lisowski, M.M. Olmstead and A.L Balch.

Preparation and Structural Characterization of a Six-Coordinate 21-Thiaporphyrin Complex: RhIII(STPP)Cl2 (STPP = Tetraphenyl-21-thiaporphyrin Anion).

Inorganic Chemistry, 28: 3328-3331.    

Balch, A.L., B.J. Davis and M.M. Olmstead.

Bonding of Sulfur Dioxide to the Metallomacrocycle Ir2(CO)2Cl2(m-Ph2PCH2)2AsPh)2 and Its Gold(I) Adduct [Ir2Au(CO)Cl2(m-(Ph2PCH2)2AsPh2]+.

Inorganic Chemistry, 28: 3148-3153.    

Arasasingham, R.E., A.L. Balch, C.R. Cornman and L. Latos-Grazynski.

Dioxygen Insertion into Iron(III)-Carbon Bonds.  NMR Studies of the Formation and Reactivity of Alkylperoxo Complexes of Iron(III) Porphyrins.

Journal of the American Chemical Society, 111: 4357-4363.     

Balch, A.L., M.M. Olmstead, D.E. Oram, P.E. Reedy Jr. and S.H. Reimer.

Complexation of Tin(II) by the Iridium Metallomacrocycle, (Ir2(CO)2Cl2(m-Ph2PCH2As(Ph)CH2PPh2)2, a Novel Receptor and Sensor of Tin(II).

Journal of the American Chemical Society, 111: 4021-4028.    

Balch, A.L., B.G. Davis, F. Neve and M.M. Olmstead.

Selective Dihydrogen Addition to Iridium Ions in Polynuclear Complexes Derived from the Metallomacrocycles M2(CO)2Cl2{(m-Ph2PCH2)2AsPh}2 (M = Ir or Rh).

Organometallics, 8: 1000-1007.    

Latos-Grazynski, L., J. Lisowski, M.M. Olmstead and A.L. Balch.

Five-Coordinate Complexes of 21-Thiaporphyrin.  The Preparation, Spectra, and Structures of Iron(II), Nickel(II) and Copper(II) Complexes.

Inorganic Chemistry,  28: 1183-1188.    

1988

Balch, A.L., K. Waggoner and M.M. Olmstead.

A Novel Oxidation Resulting from the Reaction of Tin(II) Chloride with Ir2(CO)2(m-S) (m-Ph2PCH2PPh2)2: The Structure of Ir2(CO)2(SnCl3)2(m-S)(m-Ph2PCH2PPh2)2.

Inorganic Chemistry  27: 4511-4513.    

Balch, A.L., M.M. Olmstead, P.E. Reedy Jr. and S. P. Rowley.

Two Modes of Chelation for Bis(diphenylphosphinomethyl)phenylarsine.  The Structures of [Au{(Ph2PCH2)2AsPh2][Au(CN)2] and Ru{(Ph2PCH2)2AsPh2Cl2.

Inorganic Chemistry  27: 4289-4294.    

Balch, A.L., M.M. Olmstead and D.E. Oram.

Synthesis and Structure of a Heterometallic-Cluster [W(CO)5SnClFe(CO)4]2 [Na2((C2H5)2O)4(C4H8O2)2] with a Novel Layered Structure.

Inorganic Chemistry  27: 4309-4312.    

Balch, A.L., M.M. Olmstead, F.Neve and M. Ghedini.

Comparisons of Cu(I), Ag(I) and Au(I) Binding to the Metallomacrocycles M2(Cl)2(CO)2{m-(Ph2PCH2)2AsPh}2 (M = Rh, Ir).  The Structures of [Rh2Cu(m-Cl)2(CO)2{m-(Ph2PCH2)2AsPh}2+ and Two Modifications of [Ir2CuI2(CO)2{m-(Ph2PCH2)2AsPh}2]+.

New Journal of Chemistry  12: 529-537  (Invited Contribution).    

Balch, A.L., L.A. Fossett, J.K. Nagle and M.M. Olmstead.

Nearly Linear Rh(I) Aggregates.  Chemical and Spectroscopic Behavior of [Rh3(CNCH3)6{m-(Ph2PCH)2PPh}2]3+ and Its Oxidation Products.

Journal of the American Chemical Society, 110: 6732-6738.    

Arasasingham, R.D., A.L. Balch and M.M. Olmstead.

Synthesis and Structural Characterization of Octaethyl-17-thiochlorin and Octaethyl-7,17-dithioisobacteriochlorin.

Heterocycles  27: 2111-2118.     .

Balch, A.L. and D.E. Oram.

Di-rhodium(I) and Tri-rhodium(I) Complexes with Bridging Bis(dimethylphosphinomethyl) methylphosphine.

Journal of Organometallic Chemistry  349: 245-256.    

Balch, A.L., M.M. Olmstead and S.P. Rowley.

Metallomacrocycles Built from Mercury(II) and Bis-(diphenyphosphinomethyl) phenylarsine.

Inorganic Chemistry  27: 2275-2278.    

Balch, A.L., Y.-W. Chan, M.M. Olmstead, M.W. Renner and F.E. Wood.

Rupture and Repair of the Porphyrin Inner Core: Carbon-Nitrogen Bond Breaking and Formation in Ruthenium Complexes of an N,N'-Bridged Porphyrin.

Journal of the American Chemical Society  110: 3897-3902.    

Arasasingham, R.D. A.L. Balch and L. Latos-Grazynski.

Peroxy Intermediates in the Reactions of Iron (II) Porphyrins and Alkyl Iron (III) Porphyrins with Dioxygen.

"Studies in Organic Chemistry", W. Ando and Y. Moro-oka, Eds., Elsevier, Amsterdam, Vol. 33, pp. 417-424.     (Invited Contribution).

Balch, A.L.

Metallomacrocycles: Novel Amphoteric Macrocycles with Metal Ions and Traditional Lewis Bases as Binding Sites.

Pure and Applied Chemistry  60: 555-559.     (Invited Contribution)

Balch, A.L., L.A. Fossett, M.M. Olmstead and P.E. Reedy Jr.

Concerted Motion of Carbon Monoxide and Bridging Chloride Ligands in the Heterotrinuclear Complex [Ir2Rh(m-Cl){m-(Ph2PCH2)2AsPh}2][BPh4]2.

Organometallics  7:  430-436.    

Balch, A.L., J.K. Nagle, D.E. Oram and P.E. Reedy Jr.

Oxidative Additions and Luminescence Involving Ir-Au-Ir Chains Formed by Binding of Gold(I) to the Metallomacrocycle Ir2Cl2(CO)2[m-Ph2PCH2As(Ph)CH2PPh2]2.

Journal of the American Chemical Society  110: 454-462.    

Balch, A.L. and D.E. Oram.

Four- and Five-Coordinate Tin(II) (Stannylene) Donors: The Crystal and Molecular Structures of W(CO)5{SnCl2(OC4H8)} and W(CO)5{SnCl2(OC4H8)2}.

Organometallics  7:  155-158.    

Nagle, J.K., A.L. Balch and M.M. Olmstead.

Tl2Pt(CN)4: A Non-Columnar, Luminescent Form of Pt(CN)42- Containing Tl-Pt Bonds.

Journal of the American Chemical Society  110: 319-321.     

1987

Eisenschmid, T.C., Kirss, R.U., Deutsch, P.P., Hommeltoft, S.I., Eisenberg, R., Bargon, J., Lawler, R.G. and A.L. Balch.

Para Hydrogen Induced Polarization in Hydrogenation Reactions.

Journal of the American Chemical Society  109: 8089-8091.     

Arasasingham, R.D., A.L. Balch, M.M. Olmstead and M.W. Renner.

Insertion of Manganese and Cobalt into Octaethylporphyrin N-Oxide.  The Formation of Layered Diporphyrin Structures Joined through M-O-N Links.

Inorganic Chemistry  26: 3562-3568.     

Arasasingham, R.D., A.L. Balch and L. Latos-Grazynski.

Identification of Intermediates and Products in the Reaction of Porphyrin Iron(III) Alkyl Complexes with Dioxygen.

Journal of the American Chemical Society  109: 5846-5847.    

Balch, A.L., L.A. Fossett and M.M. Olmstead.

Folding and Unfolding of a Trirhodium Chain about an Isocyanide Ligand.  The Structure of [Rh3{m-(Ph2PCH2)2PPh}2(n-C4H9NC)5CO]3+ as a Solid and in Solution.

Organometallics  6: 1827-1829.    

Latos-Grazynski, L., J. Lisowski, M.M. Olmstead and A.L. Balch.

21-Thiatetra-p-tolylporphyrin and Its Copper(II) Bicarbonate Complex.  Structural Effects of Copper-Thiophene Binding.

Journal of the American Chemical Society  109:  4428-4429.    

Bailey, D.A., A.L. Balch, L.A. Fossett, M.M. Olmstead and P.E. Reedy Jr.

A Novel Case of Metal-Metal Bond Mobility.  The Structure and Fluxional Behavior of [Rh2Pd(CO)2(m-Cl)Cl2{m-(Ph2PCH2)2AsPh}2][BPh4] and Related Compounds.

Inorganic Chemistry  26: 2413-2418.    

Balch, A.L., J.K. Nagle, M.M. Olmstead and P.E. Reedy Jr.

Formation of Luminescent, Bent Ir-Tl-Ir and Ir-Pb-Ir Chains through the Binding of Thallium(I) and Lead(II) to the Iridium Metallomacrocycle, Ir2(CO)2Cl2{m-(Ph2PCH2)2AsPh}2.

Journal of the American Chemical Society  109: 4123-4124.    

Balch, A.L., D.E. Oram and P.E. Reedy Jr.

Three-Fragment, Two-Centered Oxidative Addition of AuCl4- to Ir2(CO)2Cl2{m-(Ph2PCH2)2AsPh}2.

Inorganic Chemistry  26: 1836-1837.    

Balch, A.L. and D.E. Oram.

Low-Coordinate Lead(II) Complexes with PbP2C and PbP4 Coordination.  The Preparations and Structures of Pb[(Ph2P)CH]2 and Pb[(Ph2P)2CSiMe3)]2.

Inorganic Chemistry  26: 1906-1912.    

Balch, A.L. and D.E. Oram.

New Polyfunctional Ligands Derived from Bis(diphenylphosphino)methanide.

Phosphorous and Sulfur  30: 101-104.    

Balch, A.L., M. Ghedini, D.E. Oram, and P.E. Reedy Jr.

Geometric Changes Occurring on Silver Chloride Binding by the Metallomacrocycle Rh2(CO)2Cl2{m-(Ph2PCH2)2AsPh}2.

Inorganic Chemistry  26: 1223-1229.    

Wang, H.-H., L.H. Pignolet, P.E. Reedy Jr., M.M. Olmstead and A.L. Balch.

1,3-Bis(diphenylphosphino)propane Bridged Complexes.  The X-ray Crystal and Molecular Structure of Ir2(CO)2Cl2{m-Ph2P(CH2)3PPh2}2, its Reactions with H2 and O2, and the Structure of Ir2(CO)2Cl2O2{m-Ph2P(CH2)3PPh2}2.

Inorganic Chemistry  26: 377-383.    

1986

Balch, A.L. Y.W. Chan, M.M. Olmstead and M.W. Renner.

[N-(2,2-Bis(p-chlorophenyl)vinyl) tetraphenylporphyrinato] iron(II) chloride, Its Structure and Comparison with Other Products Obtained through the Reaction of 1,1-Bis(p-chlorophenyl)-2,2,2-trichloroethane (DDT) and Iron Porphyrins.

Journal of Organic Chemistry 51: 4651-4656.    

Penner-Hahn, J.E., K.S. Eble, T.J. McMurry, M.W. Renner, A.L. Balch, J.T. Groves, J.H. Dawson and K.O. Hodgson.

Structural Characterization of Horseradish Peroxidase Using EXAFS Spectroscopy.  Evidence for Fe=O Ligation in Compounds I and II.

Journal of the American Chemical Society  108: 7819-7825.    

Balch, A.L., L.A. Fossett and M.M. Olmstead.

A Second Example of Rupture and Realignment of the Phosphine Bridge Orientation in Polynuclear Complexes.  The Formation and Structure of Bis-(m-2,6-bis(diphenylphosphino)pyridine) (m-iodo) (m-carbonyl) dirhodium Tetraphenylborate.

Inorganic Chemistry  25: 4526-4529.    

Chatfield, M.J., G.N. La Mar, J.T.J. Lecomte, A.L. Balch, K.M. Smith and K.C. Langry.

Identification of the Altered Pyrrole in Sulfmyoglobin and Extractable "Sulfhemin": Participation of the 4-Vinyl Group in the Saturation of the Pyrrole in One Form of Sulfmyoglobin.

Journal of the American Chemical Society  108: 7108-7110.    

Chatfield, M.J., G.N. La Mar, A.L. Balch, K.M. Smith, D.W. Parish and T.J. LePage.

Proton NMR Study of the Influence of Heme Vinyl Groups on the Formation of the Isomeric Forms of Sulfmyoglobin.

FEBS Letter  206: 343-346.    

Balch, A.L. and D.E. Oram.

Monomeric, Three-Coordinate Tin(II) and Lead(II) Complexes with an MCP2 Coordination Sphere: Sn[CH(PPh2)2]2 and Pb[CH(PPh2)2]2.

Organometallics  5: 2159-2161.    

Balch, A.L., J.C. Linehan and M.M. Olmstead.

Multiple Routes to the Formation of a Phosphine-Bridged Trirhodium Dihydride Cation, [Rh3{m-(Ph2PCH2)2PPh}2(H)2(m-Cl)2(CO)2]+.

Inorganic Chemistry  25: 3937-3942.    

Balch, A.L., L.A. Fossett, M.M. Olmstead and P.E. Reedy Jr.

Systematic Mixed-Metal Cluster Synthesis.  The Preparation, Structure, and Spectroscopic Properties of Bis-(diphenylphosphinomethyl) phenylarsine - Bridged Complexes Containing Nearly Linear Rh3, RhIrRh, IrRhIr, Ir3 Chains.

Organometallics 5: 1929-1937.     

Balch, A.L. and Y.W. Chan.

A Novel Oxygen Atom Transfer Reaction.  Isomerization of Nickel(II) Octaethylporphyrin N-oxide to Nickel Octaethyloxochlorin.

Inorganic Chimica Acta  115: L45-L46.    

Balch, A.L., L.A. Fossett, R.R. Guimerans, M.M. Olmstead, and P.E. Reedy Jr.

X-ray Crystal Structure and Structural Dynamics of [Ir3{m-(Ph2PCH2)2AsPh}2(m-CO)2(CO)2(m-Cl)Cl]+ and Related Rhodium Complexes.

Inorganic Chemistry  25: 1397-1404.    

Balch, A.L., and M.W. Renner.

Spectroscopic Studies of Phenyl Iron(IV) Porphyrin Complexes and Their Conversion into Iron(II) N-Phenylporphyrins.

Journal of the American Chemical Society  108: 2603-2608.    

Balch, A.L., L.A. Fossett, R.R. Guimerans, M.M. Olmstead, P.E. Reedy Jr. and F.E. Wood.

Preparation and Structural Dynamics of Phosphine-Bridged Trirhodium Chains.  Observation of Facile Bridge/Terminal Interchange of Anionic Ligands or Carbon Monoxide.

Inorganic Chemistry  25: 1248-1253.    

Balch, A.L., L.A. Fossett, J. Linehan, and M.M. Olmstead.

Acetylene Binding to Triphosphine-Bridged, Trirhodium Chains.  The Preparation and X-ray Crystal Structure of the Dimetalated Olefin Complex [Rh3(m-(Ph2PCH2)2PPh)2(m-CO)(CO)(m-Cl)Cl(m-CH3O2CC=CCO2CH3)][BPh4].

Organometallics  5: 691-698.    

Balch, A.L. M.M. Olmstead, and D.E. Oram.

Synthesis, Structure, and Structural Dynamics of a Remarkably Crowded Rhodium(I) Dimer: [Rh2((Me2PCH2)2PMe)2(CO)2]-[B(C6H5)4]2.

Inorganic Chemistry  25: 298-303.    

Chatfield, M.J., G.N. La Mar, A.L. Balch, and J.T.J. Lecomte.

Multiple Forms of Sulfmyoglobin as Detected by 1H Nuclear Magnetic Resonance Spectroscopy.

Biochemical and Biophysical Research Communications, Vol. 135, No. 1, pp.309-315.    

Balch, A.L., and M.W. Renner.

1H Nuclear Magnetic Resonance Studies of Iron (II) Porphyrin Complexes with Axial Aryl Ligands.

Inorganic Chemistry  25: 303-307.    

1985

Balch, A.L., J.C. Linehan, and M.M. Olmstead.

Site-Selective Dihydrogen Addition to a Trirhodium Chain.  Preparation and Structure of [Rh3(m-(Ph2PCH2)2PPh)2(H)2(CO)2(m-Cl)2][BPh4].

Inorganic Chemistry  24: 3975-3976.    

Balch, A.L., H. Hope, and F.E. Wood.

Complexation of Tin (II) Chloride by a Novel Macrocycle Containing Rhodium and Nitrogen Binding Sites.  The Preparation and X-ray Crystal Structure of Rh2Sn2(CO)2Cl6[m-2,6-bis(diphenylphosphino)pyridine]2.

Journal of the American Chemical Society  107: 6936-6941.    

Balch, A.L., Y.W. Chan, and M.M. Olmstead.

A Complex Containing a Ni-O Unit at the Center of a Porphyrin.  The X-ray Structure of the Nickel(II) Complex of Octaethylporphyrin N-Oxide Dianion.

Journal of the American Chemical Society  107: 6510-6514.    

Balch, A.L., L.A. Fossett, M.M. Olmstead, D.E. Oram, and P.E. Reedy Jr. Metal Ion Complexation by Rhodium and Iridium Metallomacrocycles.

The Preparation and X-ray Crystal Structures of Rh2(CO)2Cl2(m-Ph2PCH2As(Ph)CH2PPh2)2 and [Rh2Pd(CO)2Cl3(m-Ph2PCH2As(Ph)CH2PPh2)2][BPh4].

Journal of the American Chemical Society.  107: 5272-5274.    

Balch, A.L., R.R. Guimerans, J. Linehan, M.M. Olmstead, and D.E. Oram.

Metal-Metal Interactions in Binuclear Complexes.  Structural Characterization of Isomers Resulting from Apparent Internal Oxidative Addition of a Platinum-Chlorine Bond to a Rhodium (I) Center.

Organometallics  4: 1445-1451.    

Balch, A.L., R.J. Cheng, G.N. La Mar and L. Latos-Grazynski.

Proton Nuclear Magnetic Resonance Studies of Iron Porphyrin Complexes with a Vinyl Carbene Inserted between Iron and a Pyrrole Nitrogen.

Inorganic Chemistry  24: 2651-2656.    

Balch, A.L., G.N. La Mar, L. Latos-Grazynski, and M.W. Renner.

Studies of the Chemical Oxidation of Iron (II) Complexes of N-Methylporphyrins to Form the Corresponding Iron (III) Complexes.

Inorganic Chemistry  24: 2432-2436.    

Balch, A.L., R.R. Guimerans, J. Linehan and F.E. Wood.

Preparation and Structure of Mono- and Binuclear Complexes of (Diphenylarsino)(diphenylphosphino)methane including the X-ray Crystal Structure of trans-Rh(CO)Cl(m-Ph2AsCH2PPh2)2-cis-PtCl2.

Inorganic Chemistry  24: 2021-2026.    

Balch, A.L., and M.M. Olmstead.

Small Rhodium Aggregates with Unusual Oxidation States.  The Synthesis and Structure of [Rh3((Ph2PCH2)2PPh)2(CO)I4[BPh4]Ê0.77 Acetone.

Israel Journal of Chemistry  25: 189-195.    

Balch, A.L., G.N. La Mar, L. Latos-Grazynski, M.W. Renner, and V. Thanabal.

Nuclear Magnetic Resonances Studies of Axial Amine Coordination in Synthetic Ferryl, [(FeIVO)2+], Porphyrin Complexes and in Ferryl Myoglobin.

Journal of the American Chemical Society  107: 3003-3007.    

Balch, A.L., L. Latos-Grazynski and M.W. Renner.

Oxidation of Red Ferryl [(FeIVO)2+] Porphyrin Complexes to Green Ferryl [(FeIVO)2+] Porphyrin Radical Complexes.

Journal of the American Chemical Society  107: 2983-2985.    

Balch, A.L., Y.W. Chan, G.N. La Mar, L. Latos-Grazynski, and M.W. Renner.

Proton and Deuterium Nuclear Magnetic Resonance Studies on Iron(II) Complexes of N-Substituted Porphyrins.

Inorganic Chemistry  24: 1437-1443.    

Balch, A.L., L.A. Fossett, R.R. Guimerans, and M.M. Olmstead.

Preparation and Structure of [Rh3(m-(Ph2PCH2)2PPh)2(m-CO)(CO)(m-X)X][BPh4]  (X = Cl, Br, I), a Ligand-Poor Set of Trirhodium Clusters.

Organometallics  4: 781-788.    

Balch, A.L., Y.W. Chan, M.M. Olmstead, and M.W. Renner.

Structure of Octaethylporphyrin N-Oxide and the Characterization of its Nickel(II) and Copper (II) Complexes.

Journal of the American Chemical Society  107: 2393-2398.    

Balch, A.L., R.R. Guimerans, and J. Linehan.

Mono- and Polynuclear Transition-Metal Complexes of the Linear, Small-Bite Tris-(phosphine) Bis[(diphenylphosphino)methyl)]phenylphosphine.

Inorganic Chemistry  24: 290-296.    

1984

Wood, F.E., M.M. Olmstead, J.P. Farr, and A.L. Balch.

The Synthesis and Structural Characterization of (2-Pyridyldiphenylphosphine oxide)platinum(IV)tetrabromide.  A Chelating Phosphine Oxide with a Substantially Bent Pt-O-Pt Angle.

Inorg. Chim. Acta  24: 290-296.    

Wood, F.E., J. Hvoslef, H. Hope, and A.L. Balch.

2,6-Bis(diphenylphosphino)pyridine as a Bridging Ligand in Planar Complexes of Platinum(II) and Palladium(II).

Inorganic Chemistry  23: 4309-4315.    

Ladd, J.A., H. Hope, and A.L. Balch.

Lewis Acid Bonding to Triruthenium and Triosmium Clusters.  The Crystal and Molecular Structure of Ru3(m-Ph2PCH2PPh2)2(CO)8(m-AgO2CCF3)Ê1/2-CH2Cl2 and Spectroscopic Studies of Related Adducts.

Organometallics  3: 1838-1846.    

Balch, A.L., Y.-W Chan, R.-J. Cheng, G.N. La Mar, L. Latos-Grazynski, and M.W. Renner.

Oxygenation Patterns for Iron(II) Porphyrins.  Peroxo and Ferryl (FeIVO) Intermediates Detected by 1H Nuclear Magnetic Resonance Spectroscopy during the Oxygenation of (Tetramesityl-porphyrin)iron(II).

Journal of the American Chemical Society  106: 7779-7785.    

Rutherford, N.M., M.M. Olmstead and A.L. Balch.

Bridged or Nonbridged Structures for Dinuclear Metal Complexes.  The Case of Tetrakis(methyl isocyanide) dipalladium(I) Iodide: An Unbridged Compound.

Inorganic Chemistry  26: 2834-2837.    

Ladd, J.A., M.M. Olmstead and A.L. Balch.

Redox-Active Binuclear Complexes.  Preparation, Oxidation, and Structure of Rh2(Ph2PCH2PPh2)2(1,2-O2C6Cl4)(CO).

Inorganic Chemistry  23: 2318-2323.    

Balch, A.L., M.M. Olmstead and R.R. Guimerans.

Trinuclear Complexes Bridged by Bis[(diphenylphosphino)-methyl]phenylphosphine.  The Synthesis and Structure of [Rh3(m-{Ph2PCH2}2PPh)2(m-CO)=(CO)(m-S2COEt)(S2COEt)]-[BPh4]ÊOÊ5CH2Cl2 and Related Binuclear Compounds.

Inorganica Chimica Acta  84: L21-L23.    

Chan, Y.W. F.E. Wood, M.W. Renner, H. Hope and A.L. Balch.

Remarkable Disruption of a Porphyrin.  Insertion of a Ruthenium Atom into a Pyrrole Carbon-Nitrogen Bond of an N,N'-Vinyl-Bridged Porphyrin.

Journal of the American Chemical Society, 106, 3380-3381.    

Balch, A.L., R.R. Guimerans and M.M. Olmstead.

Reactivity of Bis[(diphenylphosphino)methyl]phenylphosphine-Bridged Trinuclear Rhodium Complexes: Cluster Families Related by Reversible Carbon Monoxide Binding and Oxidative Addition.

Journal of Organometallic Chemistry  268: C38-C42.    

Guimerans, R.R., F.E. Wood and A.L. Balch.

Factors Affecting Metal-Metal Interactions in Binuclear Complexes.  Synthesis and Structure of the Face-to-Face Complex trans-Rh(CO)Cl (m-Ph2AsCH2PPh2)2-cis-PtCl2.

Inorganic Chemistry  23: 1307-1308.    

Balch, A.L.

Odd Oxidation States of Palladium and Platinum.

Comments in Inorganic Chemistry  3: 51-67.     (Invited contribution.)

1983

Farr, J.P., M.M. Olmstead, N.M. Rutherford, F.E. Wood and A.L. Balch.

Linking Molybdenum or Tungsten with Platinum.

Organometallics  2: 1758-1762.    

Penner-Hahn, J.E., T.J. McMurry, M. Renner, L. Latos-Grazynski, K.S. Eble, I.M. Davis, A.L. Balch, J.T. Groves, J.H. Dawson and K. O. Hodgson.

X-ray Absorption Spectroscopic Studies of High Valent Iron Porphyrins: Horseradish Peroxidase Compounds I and II and Synthetic Models.

Journal of Biological Chemistry  258: 12761-12764.    

Wood, F.E., J. Hvoslef and A.L. Balch.

Rupture and Realignment of the Bridging Phosphine Framework in the Reactions of Polynuclear Rhodium Complexes of 2,6-Bis(diphenylphosphino)pyridine.

Journal of the American Chemical Society  105: 6986-6987.    

Guimerans, R.R. and A.L. Balch.

Head-to-Head and Head-to-Tail Isomers of Compounds with Bridging (Diphenylarsino) (diphenylphosphino) methane Ligands.

Inorganica Chimica Acta  77: L177-L178.    

Chan, Y.W., M.W. Renner and A.L. Balch.

Insertion of Zero Valent Metals into the C-N Bonds of N,N'-Bridged Porphyrins.

Organometallics  2: 1888-1889.    

Farr, J.P., F.E. Wood and A.L. Balch.

Head-to Head and Head-to-Tail Isomers of Binuclear Complexes of Platinum (I) and Palladium(I) Involving 2-(Diphenylphosphino)pyridine as a Bridging Ligand.

Inorganic Chemistry  22: 3381-3393.    

Wood, F.E., M.M. Olmstead and A.L. Balch.

Phosphine Ligands for the Construction of Polynuclear Complexes II.  2,6-Bis(diphenylphosphino)pyridine Complexes of Palladium(II) and Rhodium(I).

Journal of the American Chemical Society  105: 6332-6334.    

Olmstead, M.M., R.R. Guimerans, J.P. Farr and A.L. Balch.

Bis[(diphenylphosphino)methyl]phenylphosphine as a Chelating and Bridging Ligand.  The Preparations and Molecular Structure of Palladium Complexes.

Inorganica Chimica Acta  75: 199-208.    

Olmstead, M.M., R.R. Guimerans and A.L. Balch.

Flexibility in Complexes Bridged by Bis[(diphenylphosphino)-methyl]phenylphosphine.  Structure of [Rh3(m-(Ph2PCH2)2PPh)2(m-I)2(m-CO)(CO)2][BPh4].

Inorganic Chemistry  22: 2473-2474.    

Guimerans, Rosalvina R., M. M. Olmstead and A.L. Balch.

Characterization of Chelating Bis[(diphenylphosphino)-methyl]phenylphosphine as a Bridging Ligand in Bi- and Trinuclear Complexes.

Inorganic Chemistry  22: 2223-2224.    

Guimerans, R.R., M.M. Olmstead and A.L. Balch.

Phosphine Ligands for the Construction of Polynuclear Complexes  1.  Bis(diphenylphosphinomethyl) phenylphosphine Complexes of Palladium (II) and Rhodium(I).

Journal of the American Chemical Society  105: 1677-1679.    

Farr, J.P., M.M. Olmstead, F.E. Wood and A.L. Balch.

Preparation of Heterobinuclear Rhodium/Platinum Complexes Prepared Using 2-(diphenylphosphino)pyridine as a Connecting Ligand.

Inorganic Chemistry  22: 1229-1235.    

Farr, J.P., M.M. Olmstead, F.E. Wood and A.L. Balch.

The Formation and Reactivity of Some Heterobinuclear Rhodium/Platinum Complexes with 2-(diphenylphosphino)pyridine as a Bridging Ligand.

Journal of the American Chemical Society  105: 792-798.    

Wood, F.E., A.L. Balch.

Natural Abundance 195Pt Nuclear Magnetic Resonance Studies of Some Platinum(II) Nitro Complexes.

Inorganica Chimica Acta Letters.  76: L63-L64.    

Balch, A.L.

Binuclear, Phosphine Bridged Complexes.  Progress and Prospects.

Book Chapter in "Homogeneous Catalysis with Metal Phosphine Complexes"  L.H. Pignolet, ed.  Plenum Press, New York.  167-213    

La Mar, G.N., J.S. de Ropp, L. Latos-Grazynski, A.L. Balch, R.B. Johnson, K.M. Smith, D.W. Parish and R. -J. Cheng.

Proton NMR Characterization of the Ferryl Group in Model Heme Complexes and Hemoproteins:  Evidence for the Fe(IV)=O Group in Ferryl Myoglobin and Compound II of Horseradish Peroxidase.

Journal of the American Chemical Society  105: 782-787.    

1982

Olmstead, M.M., R. -J. Cheng and A.L. Balch.

X-ray Crystallographic Characterization of an Iron Porphyrin with a Vinylidene Carbene Inserted into an Iron Nitrogen Bond.

Inorganic Chemistry  21: 4143-4148.    

Wood, F.E., C.T. Hunt and A.L. Balch.

195Pt and 31P Nuclear Magnetic Resonance Studies of the Binding of the cis-Pt(NH3)22+ Moiety to Phosphate in Aqueous Solution.

Inorganic Chimica Acta Letters  67: L19-L20.    

Latos-Grazynski, L., A.L. Balch and G.N. La Mar.

Utility of Proton Hyperfine Shifts in Elucidating the Electronic Structure of Horseradish Peroxidase Compounds I and II and their Model Compounds.

Book Chapter in "Electrochemical and Spectrochemical Studies of Biological Redox Components,: K. Kadish, ed.  American Chemical Society Advances in Chemistry Series  201: 661-674.    

Maisonnat, A., J.P. Farr, M.M. Olmstead, C.T. Hunt and A.L. Balch.

The Preparation of Binuclear Complexes Using 2-(Diphenylphosphino)-pyridine as a Bridging Ligand.  The Synthesis of Some Ruthenium Complexes and Their Interaction with Palladium Complexes.

Inorganic Chemistry  21: 3961-3967.    

Latos-Grazynski, L., R.-J. Cheng, G.N. La Mar and A.L. Balch.

Oxygenation Patterns for Substituted Meso-Tetraphenylporphyrin Complexes of Iron(II).  Spectroscopic Detection of Dioxygen Complexes in the Absence of Amines.

Journal of the American Chemical Society  104: 5992-6000.    

Balch, A.L. and L.S. Benner.

Binuclear Transition Metal Complexes Bridged by Bis(diphenylphosphino)methane.

Inorganic Syntheses  21: 47-51.    

Olmstead, M.M., C.-L. Lee and A.L. Balch.

The Synthesis and Structure of [t-(C4H9NC)2Pd{(C6H5)PCH2P(C6H6)2}2][B(C6H5)4]2, a Compound with Two Monodentate Diphosphine Ligands.

Inorganic Chemistry  21: 2712-2716.    

Cheng, R.J., L. Latos-Grazynski and A.L. Balch.

The Preparation and Characterization of Some Hydroxy Complexes of Iron(III) Porphyrins.

Inorganic Chemistry  22: 2412-2418.    

Lee, C.-L., C.T. Hunt and A.L. Balch.

Addition of Carbon Monoxide and Methyl Isocyanide to Methyl Palladium A-Frame Complexes and Some Reactions of the Product Acyl Complexes.

Organometallics  1: 824-829.    

Hunt, C.T., A.L. Balch.

Scrambling of Halide Ligands Between Palladium (II) and Between Palladium(I) Complexes of Bis(diphenyl-phosphino) methane.  Observation of Unusual Temperature Dependent Phosphorous-31 Nuclear Magnetic Resonance Chemical Shifts.

Inorganic Chemistry  21: 1641-1644.    

Hunt, C.T., A.L. Balch.

Ambidentate Binding of Thiocyanate to Palladium.  31P NMR Observations of the Distribution of Linkage Isomers in (diphosphine)Pd(CNS)2 and (diphosphine)2Pd2(CNS)2.

Inorganic Chemistry  21: 1242-1246.    

1981

Olmstead, M.M., A. Maisonnat, J.P. Farr and A.L. Balch.

Chelating 2-(Diphenylphosphino)pyridine.   Synthesis and Structure of Dichlorodicarbonyl (2-(diphenylphosphino)pyridine)ruthenium (II).`

Inorganic Chemistry  20: 4060-4064.    

Lee, C.-L., C.T. Hunt and A.L. Balch.

Novel Reactions of Metal-Metal Bonds.   Reactions of Pd2{(C6H5)2PCH2P(C6H5)2}2Cl2 with Acetylenes, Olefins and Isothiocyanates.

Inorganic Chemistry  20: 2498-2504.    

Latos-Grazynski, L., R.J. Cheng, G.N. La Mar and A.L. Balch.

Reversible Migration of an Axial Carbene Ligand into an Iron-Nitrogen Bond of a Porphyrin.  Implications for High Oxidation States of Heme Enzymes and Heme Catabolism.

Journal of the American Chemical Society  103: 4270-4272.    

Balch, A.L., C.T. Hunt, C.L. Lee, M.M. Olmstead and J.P. Farr.

Organo Halide Addition to [Pd2(Ph2PCH2PPh2)3.  Preparation of Novel Methylene- and Phenylene-Bridged Complexes by Two-Center, Three-Fragment Oxidative Addition.

Journal of the American Chemical Society  103: 3764-3772.    

Hunt, C.T., G.B. Matson, A.L. Balch.

Chemical and 31P-NMR Spectroscopic Investigations of (Ph3P)3(CO)Pt3(m-S).  A Molecule with a Robust Pt2S Core.  Applications of Selective Population Transfer to Isotopomer Identification.

Inorganic Chemistry  20: 2270-2276.    

Olmstead, M.M., J.P. Farr and A.L. Balch.

An Asymmetric Molecular A-Frame: The Crystal Structure of [Pd2(Ph2PCH2PPh2)2(m-I)(CH3)I]-[BF4]Ê1/2H2O.

Inorganica Chimica Acta  52: 47-54.    

Farr, J.P., M.M. Olmstead, C.H. Hunt and A.L. Balch.

Rhodium Complexes of 2-(Diphenylphosphino)pyridine.  X-ray Crystal and Molecular Structure of Rh2[(C6H6)2PC5H4N]2(m-CO)Cl2 and some Chemical Transformations of this Complex.

Inorganic Chemistry  20: 1182-1187.    

Maisonnat, A., J.P. Farr and A.L. Balch.

Dinuclear Palladium Complexes of 2-Diphenylphosphinopyridine.

Inorganic Chimica Acta  53: L217-L218.    

Hunt, C.T. and A.L. Balch.

Halogen Additions to Bis(diphenylphosphino)methane Complexes of Palladium.  Interrelationships of Monomeric and Dimeric Complexes of Pd(II), Pd(I) and Pd(0).

Inorganic Chemistry  20: 2267-2270.    

1980

Farr, J.P., M.M. Olmstead and A.L. Balch.

2-(Diphenylphosphino)pyridine as a Bridging Ligand.  Synthesis and Structure of Rh2(Ph2Ppy)2(m-CO)Cl2 and RhPd(Ph2Ppy)2(CO)Cl3.

Journal of the American Chemical Society  102: 6654-6656.    

Chin, D.-H., G.N. La Mar, and A.L. Balch.

Role of Ferryl (FeO2+) Complexes in Oxygen Atom Transfer Reactions.  Mechanism of Iron(II) Porphyrin Catalyzed Oxygenation of Triphenylphosphine.

Journal of the American Chemical Society  102: 5945-5947.    

Balch, A.L.

Metal-Metal Bond Making and Breaking in Binuclear Complexes with Phosphine Bridging Ligands.

Book chapter, "Reactivity of Metal-Metal Bonds,"  ACS Symposium Series #155, 167-185.    

Balch, A.L.

Novel Reactions of Dinuclear Metal Complexes Containing Bis(diphenylphosphino)methane as a Bridging Ligand.

Book Chapter in "Catalytic Aspects of Metal Phosphine Complexes."  E.C. Alyea and D.W. Meek, eds., American Chemical Society Advances in Chemistry Series  196: 243-256.    

Lindsay, C.H., L.S. Benner and A.L. Balch.

Di- and Tri- (tertiary phosphine) Complexes of Palladium (I).

Inorganic Chemistry  19: 3503-3508.    

Balch, A.L.

The Solution Properties of One-Dimensional Metal Chain Complexes.

Book Chapter in "Extended Linear Chain Complexes."  J. Miller, ed.  Plenum Press New York, Vol. 1, pp. 1-31.    

Chin, D.H., G.N. La Mar and A.L. Balch.

On the Mechanism of Autoxidation of Fe(II) Porphyrins.  The Detection of a Peroxobridged Fe(III) Porphyrin Dimer and the Mechanism of its Thermal Decomposition to the oxo-bridged Fe(III) Porphyrin Dimer.

Journal of the American Chemical Society  102: 4344-4350.    

Balch, A.L. and J. Yow.

Association of d6 and d8 Metal Complexes in Solution.  The Formation of (p-CH3C6H4NH2)Ir(CO)2Cl/(p-CH3C6H4NH2)Ir(CO)2ClI2.

Journal of the American Chemical Society  102: 1448-1449.    

Chin, D. -H., A.L. Balch and G.N. La Mar.

Formation of Porphyrin Ferryl (FeO2+) Complexes through the Addition of Nitrogen Bases to Peroxo-Bridged Iron(III) Porphyrins.

Journal of the American Chemical Society  102: 1446-1448.    

1979

Balch, A.L., C.-L. Lee, C.H. Lindsay and M.M. Olmstead.

Insertion of Acetylenes in the Pd-Pd Bond of Pd2(Ph2PCH2PPh2)2Cl2.

Journal of Organometallic Chemistry 177: C22-C26.    

Balch, A.L., L.S. Benner and M.M. Olmstead.

Novel Reaction of Metal-Metal Bonds.  Addition of Sulfur Dioxide and Sulfur to Pd2(Ph2PCH2PPh2)2Cl2 and the Oxidation of Coordinated Sulfide.

Inorganic Chemistry  18: 2996-3003.    

Brant, P., L.S. Benner and A.L. Balch.

X-ray Photoelectron Spectra of Binuclear Palladium-Palladium-Bonded Complexes and Their Insertion Products.

Inorganic Chemistry  18: 3422-3427.    

Olmstead, M.M., C.H. Lindsay, L.S. Benner and A.L. Balch.

Dinuclear Rhodium Complexes with Three and Four Bridging Ligands.  The Preparation and Crystal Structure of [Rh2(Ph2PCH2PPh2)2(m-Cl)(m-CO)(CO)2] [Rh(CO)2Cl2]ÊCH2Cl2.

Journal of Organometallic Chemistry  179: 289-300.    

Balch, A.L. and M.M. Olmstead.

Three Center Oxidative Addition.  The Formation, Structure, and Dissociation of (PhCH2NC)12Rh3I23+and Related Cations.

Journal of the American Chemical Society  101: 3128-3129.    

Balch, A.L., J.J. Watkins and D.J. Doonan.

Hydrogen Bonding to Coordinated Imidazole.  Association of 1,10-Phenanthroline and Other Bases with bis-(Imidazole)metalloporphyrins.

Inorganic Chemistry  18: 1228-1231.    

Balch, A.L., J.W. Labadie and G. Delker.

Further Studies of Diphosphine- and Diarsine-Bridged Rhodium Complexes.

Inorganic Chemistry  18: 1224-1227.    

Balch, A.L. and R.D. Cooper.

Bidentate Amine as Bridges between M(CO)2Cl  (M = Rh or Ir) Units.

Journal of Organometallic Chemistry  169: 97-105.    

Olmstead, M.M., L.S. Benner, H. Hope and A.L. Balch.

Addition of Tin(II) Chloride to Pd2(Ph2PCH2PPh2)2Cl2.   The Crystal and Molecular Structure of Pd2(Ph2PCH2PPh2)2(SnCl3)Cl.

Inorg. Chim. Acta  32: 193-198.    

1978

Balch, A.L.

The Construction of Metal-Metal Bonds by Redox Processes.

Ann. N.Y. Acad.. Sci.  313: 651-662.    

Benner, L.S., M.M. Olmstead and A.L. Balch.

Structural Characterization of a Four-Electron Donating, Doubly Bridging Isocyanide in (m-p-CH2C6H4N)Mn2(Ph2PCH2PPh2)2(CO)4.

Journal of Organometallic Chemistry  159: 289-298.    

Benner, L.S. and A.L. Balch.

Novel Reaction of Metal-Metal Bonds.   Insertion of Isocyanides and Carbon Monoxides into the Palladium-Palladium Bond of Some Pd(I) Dimers.

Journal of the American Chemical Society  100: 6099-6106.    

Benner, L.S., M.M. Olmstead, H. Hope and A.L. Balch.

Reversible Insertion of Sulfur Dioxide into Palladium-Palladium Bonds.   The Preparation and Structure of Pd2(m-SO2)(Ph2PCH2PPh2)2Cl2.

Journal of Organometallic Chemistry  153: C31-C35.    

Olmstead, M.M. and A.L. Balch.

Rhodium (II) Dimers: The Preparation and Structure of [(p-CH3C6H4NC)8Rh2I2][PF6]2.

Journal of Organometallic Chemistry  148: C15-C18.    

1977

Balch, A.L. and B. Tulyathan.

Interactions between Rhodium (I) Centers in Dimeric Complexes.

Inorganic Chemistry  16: 2840-2845.    

Olmstead, M.M., H. Hope, L.S. Benner and A.L. Balch.

Insertion of Isocyanide and Carbon Monoxide into Metal-Metal Bonds.   Preparation and Structure of [Pd2(CNCH3)3[(C6H5)2PCH2P(C6H5)2]2[PF6]2.

Journal of the American Chemical Society.   99: 5502-5503.    

Chin, D.-H, J.D. Del Gaudio, G.N. La Mar and A.L. Balch.

Detection and Characterization of the Long-Postulated Fe-OO-Fe Intermediate in the Autoxidation of Ferrous Porphyrins.

Journal of the American Chemical Society  99: 5486-5488.    

Balch, A.L. and L.S. Benner.

Isocyanide Addition to Mn2(CO)5(Ph2PCH2PPh2)2 and the Formation of a Four-Electron Doubly-Bridging Isocyanide.

Journal of Organometallic Chemistry  135: 339-343.    

Benner, L.S. and A.L. Balch.

Spin Trapping of Radicals Produced by Thermal Homolysis of L2Mn2(CO)8.

Journal of Organometallic Chemistry  134: 121-130.    

Boehm, John R. and A.L. Balch.

Preparation and Dynamic Properties of Some Dimeric Palladium (I) and Platinum (I) Complexes.

Inorganic Chemistry  16: 778-785.     In-press #2 at time of promotion (7/1/77).

Balch, A.L. and D.J. Doonan.

Mixed Valence Gold Chemistry:  Stepwise Oxidation of a Cyclic Trigold (I) Complex.

Journal of Organometallic Chemistry  131: 137-146.    

1976

Balch, A.L., J.R. Boehm, H. Hope and M. Olmstead.

The Preparation and Structure of the Linear Tripalladium Cations (CH3NC)8Pd32+ and (CH3NC)6{(C6H5)3P}2Pd32+.

Journal of the American Chemical Society  98: 7431-7432.     In-press #3 at time of promotion (7/1/77).

Balch, A.L.

Dimeric Rhodium(I) and Rhodium(II) Complexes with Bridging Phosphine or Arsine Ligands.

Journal of the American Chemical Society  98: 8049-8054.     In-press #1 at time of promotion (7/1/77).

Boehm, J.R., D.J. Doonan and A.L. Balch.

Preparation and Some Reactions of Dimeric Isocyanide Complexes of Palladium (I) and Platinum (I).

Journal of the American Chemical Society  98: 4845-4850.    

Brant, P., J.H. Enemark and A.L. Balch.

X-ray Photoelectron Spectra of Palladium and Platinum Complexes of Carbenoid and Related Ligands.

Journal of Organometallic Chemistry  114: 99-106.    

Boehm, J.R. and A.L. Balch.

Substitution Reactions of Binuclear Palladium(I) and Platinum(I) Isocyanide Complexes.

Journal of Organometallic Chemistry  112: C20-C22.    

Doonan, D.J., J.E. Parks and A.L. Balch.

A Comparison of Isomeric Carbene (Ylide) and Amidine Complexes of Cobalt (III).   An Approach to the Study of Carbon-Coordinated Imidazole.

Journal of the American Chemical Society  98: 2129-2134.    

Balch, A.L. and M.M. Olmstead.

Association of Isocyanide Complexes of Rhodium (I) and Rhodium (III) in Solution.

Journal of the American Chemical Society  98: 2354-2356.     

Balch, A.L.

Evidence for Radical Intermediates in the Addition of Tetracyanoethylene to Pentakis (methyl isocyanide) cobalt (I).

Journal of the American Chemical Society  98: 285-286.    

1975

Watkins, J.J. and A.L. Balch.

Complexes of Ferrous Phthalocyanine with Aromatic Nitroso Compounds, Isocyanides and Phosphites.

Inorganic Chemistry  14: 2720-2723.    

Girgis, A.Y. and A.L. Balch.

Catechol Oxidations.   Characterization of Metal Complexes of 3,5-Di-tert-butyl-1,2-quinone 1-(2-hydroxy-3,5-di-tert-butyl-phenyl) imine formed by the Aerial Oxidation of 3,5-Di-tert-butylcatechol in the presence of Ammonia and Divalent Metal Ions.

Inorganic Chemistry  14: 2724-2727.    

Girgis, A.Y., Y.S. Sohn and A.L. Balch.

Preparation and Oxidation of Some Quinone Adducts of Transition Metal Complexes.

Inorganic Chemistry  14: 2327-2331.    

Doonan, D.J., A.L. Balch, S.Z. Goldberg, R. Eisenberg and J.S. Miller.

Hexakis (methyl isocyanide) dipalladium (I).   Preparation, Structure and Fluxional Behavior.

Journal of the American Chemical Society  97: 1961.    

Doonan, D.J. and A.L. Balch.

A Reexamination of the Metal-Nitrogen Bond in Certain Imidazole and Pyrazole Complexes.

Journal of the American Chemical Society  97: 1403-1407.    

Boehm, J.R., A.L. Balch, K.F. Bizot and J.H. Enemark.

Oxidation of 1,1-Dimethylhydrazine by Cupric Halides.  The Isolation of a Complex of 1,1-Dimethyldiazene and a Salt Containing the 1,1,5,5,-Tetramethylformazanium Ion.

Journal of the American Chemical Society  97: 501-508.    

1974

Balch, A.L. and J.E. Parks.

Platinum and Palladium Complexes Formed by Chelative Addition of Amines to Isocyanides.

Journal of the American Chemical Society  96: 4114-4121.    

Parks, J.E. and A.L. Balch.

Gold Carbene Complexes: Preparation, Oxidation and Ligand Displacement.

Journal of Organometallic Chemistry  71: 453-463.    

Doonan, D.J. and A.L. Balch.

Carbene Complexes Resulting from the Addition of Various Amines to Isocyanide Complexes of Iron (II) and Ruthenium (II).

Inorganic Chemistry  13: 921-927.    

1973

Parks, J.E. and A.L. Balch.

Gold Carbene Complexes as Intermediates in the a-Addition of Amines to Isocyanides.

Journal of Organometallic Chemistry  57: C103-C106.    

Doonan, D.J. and A.L. Balch.

Mobility of Substituents in Metal Carbene Complexes about a FeC6 or RuC6 Core through Chelate Ring Formation.

Journal of the American Chemical Society  95: 4769-4771.    

Balch, A.L.

Oxidation of o-Quinone Adducts of Transition Metal Complexes.

Journal of the American Chemical Society  95: 2723-2724.    

Bernal, I., A. Clearfield, E.F. Epstein, J.S. Ricci, A.L. Balch and J.S. Miller.

Isomeric Conformations in a Pentacoordinated Ruthenium Compound: Crystal and Molecular Structure of the Orange and Violet Isomers of (Ph3P)2[(CF3)2C2S2]Ru(CO).

Journal of the Chemical Society Chemical Communications  39.    

Butler, W.M., J.H. Enemark, J. Parks and A.L. Balch.

Chelative Addition of Hydrazine to Coordinated Isocyanides.  The Structure of Chugaev's Red Salt.

Inorganic Chemistry  12: 451-457.    

1972

Miller, J.S. and A.L. Balch.

Preparation and Reaction of Tetrakis (methyl isocyanide) Complexes of Divalent Nickel, Palladium, and Platinum.

Inorganic Chemistry  11: 2069-2074.    

Balch, A.L.

Formation of Platinum (IV) Carbene Complexes by Oxidative Addition.

Journal of Organometallic Chemistry  37: C19.    

Sohn, Y.S. and A.L. Balch.

Oxidative Addition of o-Quinones to Complexes of Rhodium (I) and Iridium (I).

Journal of the American Chemical Society  95: 1144-1148.    

Balch, A.L. and J. Miller.

Characterization of the Complexes Obtained from the Addition of Hydrazine to Hexakis (methyl isocyanide) iron (II).

Journal of the American Chemical Society  94: 417-420.    

1971

Balch, A.L. and J. Miller.

Preparation and Reactions of Some Methyl Isocyanide Complexes of Rhodium.

Journal of Organometallic Chemistry  32: 263-268.    

Balch, A.L. and Y.S. Sohn.

Oxidative Addition of o-Quinones to Ruthenium Complexes.

Journal of Organometallic Chemistry  30: C31.    

Miller, J., and A.L. Balch.

1,2-Dithiolene Complexes of Ruthenium and Iron.

Inorganic Chemistry  10: 1410-1415.    

Sohn, Y.S. and A.L. Balch.

Thermal Oxidative-Addition of Ortho-Quinones to Low Valent Metal Complexes.

Journal of the American Chemical Society  93: 1296-1297.    

Balch, A.L.

Preparation and Oxygenation of Some Five-Coordinate Lewis Base Adducts of Iron bis-1,2-dithiolenes.

Inorganic Chemistry  10: 276-281.    

Balch, A.L.

Some Observations on Ligand-Exchange Reactions of bis-1,2-Dithiolene Complexes.

Inorganic Chemistry  10: 388-391.    

1970

Burke, A., A.L. Balch and J.H. Enemark.

Palladium and Platinum Complexes Resulting from the Addition of Hydrazine to Coordinated Isocyanide.

Journal of the American Chemical Society  92: 2555-2557.    

Epstein, E.F.,I. Bernal and A.L. Balch.

Activation of Molecular Oxygen by a Metal Complex.

Chemical Communications.136-138.    

Petridis, D., A. Burke and A.L. Balch.

Cuprous Complexes of Phenyldiazene.

Journal of the American Chemical Society  92: 428-429.    

1969

Balch, A.L.

Electron-Transfer Series Involving Sulfur-Rich, Polynuclear, Iron Dithiolene Complexes.

Journal of the American Chemical Society   91: 6962-6967.    

1969

Balch, A.L. and D. Petridis.

Coordination of Palladium by Azo and Related Functional Groups.

Inorganic Chemistry  8: 2247-2252.    

1969

Balch, A.L.

Electron-Transfer Series of the [M-O2S2] Type.   Complexes Derived from o-Mercaptophenol, 1-Mercapto-2-naphthol, and 1-Hydroxy-2-pyridinethione.

Journal of the American Chemical Society 91: 1948-1953.    

1968

Balch, A.L., I.G. Dance and R.H. Holm.

The Characterization of Dimeric Dithiolene Complexes.

Journal of the American Chemical Society  90: 1139-1145.    

1967

Balch, A.L.

Cleavage Reactions of Cobalt and Iron Dithiolate Compounds:  Five Coordinate Complexes.

Inorganic Chemistry  6: 2158-2162.    

1967

Holm, R.H., A.L. Balch, A. Davison, A. H. Maki, and T.E. Berry.

Electron Transfer Complexes of the [M-N2S2] Type: The Existence of Cation Stabilized Free Radical Complexes.

Journal of the American Chemical Society  89: 2866-2874.    

1966

Balch, A.L. and R.H. Holm.

Complete Electron-Transfer Series of the [M-N4] Type.

Journal of the American Chemical Society  88: 5201-5209.    

1966

Rohrscheid, F., A.L. Balch, and R.H. Holm.

Potential Electron Transfer Complexes of the [M-O4] Type: Synthesis and Properties of Complexes Derived from Pyrocatechol and Tetra-chloropyrocatechol.

Inorganic Chemistry  5: 1542-1551.    

1966

Balch, A.L. and R.H. Holm.

Electron Transfer Behavior of Dimeric Complexes of Cobalt and Iron with Dithiolate Ligands.

Chemical Communications 552.    

1966

Maki, A.H., T.E. Berry, A. Davison, R.H. Holm and A.L. Balch.

Concerning Cation-Stabilized Anion Free Radicals.

Journal of the American Chemical Society  88:1080-1081.    

1965

Balch, A.L., F. Rohrscheid and R.H. Holm.

New Systems of Complexes Related by Electron-Transfer Reactions.

Journal of the American Chemical Society  87: 2303-2303.    

1964

Geske, D.H. and A.L. Balch.

An Electron Spin Resonance Study of the Anion Radical of Benzocyclobutadienoquinone.

Journal of Physical Chemistry  68: 3423-3425.    

1964

Geske, D.H., J.L. Ragle, M.A. Bambenek and A.L. Balch.

Study of Steric Effects by Electron Spin Resonance Spectroscopy and Polarography.  Substituted Nitrobenzenes and Nitroanilines.

Journal of the American Chemical Society  86: 987-1002.    

1999

Lee, J. W., Ginwalla, A., Olmstead, M. M., Noll, B. C., and Balch, A. L.

Chemical Reactivity of [84]Fullerene.  Isolation and Structure of C84{Ir(CO)Cl(PMe2Ph)2}2.

Chem. Comm., in press.