Publications 2000

POWER Group – Publications 2000 - present

244. 2000 Eichler, B. E., N. J. Hardman and P. P. Power. In8(C6H3-2,6-Mes2)4 (Mes = C6H2-2,4,6-Me3): A Metal-Rich Main-Group Cluster with a Distorted Cubane Structure. Angewandte Chemie International Edition 39:383-385.

245. 2000 Allen, T. L., W. H. Fink and P. P. Power. Theoretical studies of multiple bonds in gallium-gallium and germanium-germanium compounds. Journal of the Chemical Society, Dalton Transactions, 407-412.

246. 2000 Pu, L., P. P. Power, I. Boltes, and R. Herbst-Irmer. Synthesis and Characterization of the Metalloplumbylenes (M = Cr, Mo, or W; Trip = –C6H2-2,4,6-i-Pr3). Organometallics 19:352-356.

247. 2000 Pu, L., B. Twamley, S. T. Haubrich, M. M. Olmstead, B. V. Mork, R. S. Simons, and P. P. Power. Triple Bonding to Germanium: Characterization of the Transition Metal Germylynes (h5-C5H5)(CO)2MºGe-C6H3-2,6-Mes2 (M = Mo, W; Mes = –C6H2-2,4,6-Me3) and (h5-C5H5)(CO)2MºGe-C6H3-2,6-Trip2 (M = Cr, Mo, W; Trip = –C6H2-2,4,6-i-Pr3) and the Related Single Bonded Metallogermylenes (M = Cr, W).

Journal of the American Chemical Society 122:650-656.

248. 2000 Pu, L., B. Twamley and P. P. Power. Synthesis and Characterization of 2,6-Trip2H3C6PbPbC6H3-2,6-Trip2 (Trip = C6H2-2,4,6-i-Pr3): A Stable Heavier Group 14 Element Analogue of an Alkyne. Journal of the American Chemical Society 122:3524-3525.

249. 2000 Pu, L., B. Twamley and P. P. Power. Terphenyl Ligand Stabilized Lead(II) Derivatives of Simple Organic Groups: Characterization of Pb(R)C6H3-2,6-Trip2 (R = Me, t-Bu or Ph; Trip = C6H2-2,4,6,-i-Pr3), {Pb(m-Br)C6H3-2,6-Trip2}2, py·Pb(Br)C6H3-2,6-Trip2 (py = Pyridine), and the Bridged Plumbylyne Complex [{W(CO)4}2(m-Br)(m-PbC6H3-2,6-Trip2)]. Organometallics 19:2874-2881.

250. 2000 Hardman, N. J., B. Twamley and P. P. Power. (2,6-Mes2H3C6)2BiH, a Stable, Molecular Hydride of a Main Group Element of the Sixth Period, and Its Conversion to the Dibismuthene (2,6-Mes2H3C6)BiBi(2,6-Mes2C6H3). Angewandte Chemie International Edition 39:2771-2773.

251. 2000 Wehmschulte, R. J. and P. P. Power. Primary alanes and alanates: useful synthetic reagents in aluminum chemistry. Polyhedron 19:1649-1661.

252. 2000 Eichler, B. E. and P. P. Power. [2,6-Trip2H3C6Sn(m-H)]2 (Trip = C6H2-2,4,6-i-Pr3): Synthesis and Structure of a Divalent Group 14 Element Hydride. Journal of the American Chemical Society 122:8785-8786.

253. 2000 Twamley, B., C.-S. Hwang, N. J. Hardman, and P. P. Power. Sterically encumbered terphenyl substituted primary pnictanes ArEH2 and their metallated derivatives ArE(H)Li (Ar = –C6H3-2,6-Trip2; Trip = 2,4,6-triisopropylphenyl; E = N, P, As, Sb). Journal of Organometallic Chemistry 609:152-160.

254. 2000 Twamley, B. and P. P. Power. Synthesis of the Square-Planar Gallium Species K2[Ga4(C6H3-2,6-Trip2)2] (Trip = C6H2-2,4,6-iPr3): The Role of Aryl-Alkali Metal Ion Interactions in the Structure of Gallium Clusters. Angewandte Chemie International Edition 39:3500-3503.

255. 2000 Hardman, N. J., B. E. Eichler and P. P. Power. Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri 2-2,6): a low valent gallium(I) carbene analogue. Journal of the Chemical Society, Chemical Communications, 1991-1992.

256. 2000 Hinchley, S. L.; C. A. Morrison, D. W. H. Rankin, C. L. B. Macdonald, R. J. Wiacek, A. H. Cowley, M. F. Lappert, G. Gundersen, J. A. C. Clyburne, and P. P. Power. Persistent phosphinyl radicals from a bulky diphosphine: an example of a molecular jack-in-the-box. Journal of the Chemical Society, Chemical Communications, 2045-2046.

257. 2000 Eichler, B. E. and P. P. Power. Characterization of the Sterically Encumbered Terphenyl-Substituted Species , an Unsymmetric, Group 14 Element, Methylmethylene, Valence Isomer of an Alkene, Its Related Lithium Derivative 2,6-Trip2H3C6(Me)2Sn-Sn(Li)(Me)C6H3-2,6-Trip2, and the Monomer Sn(t-Bu)C6H3-2,6-Trip2 (Trip = C6H2-2,4,6-i-Pr3). Inorganic Chemistry 39:5444-5449.

258. 2000 Eichler, B. E., B. L. Phillips, P. P. Power, and M. P. Augustine. Solid-State and High-Resolution Liquid 119Sn NMR Spectroscopy of Some Monomeric, Two-Coordinate Low-Valent Tin Compounds: Very Large Chemical Shift Anisotropies. Inorganic Chemistry 39:5450-5453.

259. 2000 Twamley, B., N. J. Hardman and P. P. Power. A terphenyl halide series: 2,6-Trip2-H3C6X (Trip = 2,4,6-triisopropyl-phenyl; X = Cl, Br, I). Acta Crystallographica Section C C56:e514-e515.

260. 2001 Eichler, B. E. and P. P. Power. Synthesis and Characterization of [Sn8(2,6-Mes2C6H3)4] (Mes = 2,4,6-Me3C6H2): A Main Group Metal Cluster with a Unique Structure. Angewandte Chemie International Edition 40:796-797.

261. 2001 Twamley, B. and P. P. Power. A donor-acceptor adduct: sterically encumbered terphenyl dichloro[2,6-bis(2,4,6-triisopropylphenyl)-phenyl]dichloro(pyridine)gallium benzene hemisolvate. Acta Crystallographica Section E E57:m88-m91.

262. 2001 Ding, Y., H. W. Roesky, M. Noltemeyer, H.-G. Schmidt, and P. P. Power. Synthesis and Structures of Monomeric Divalent Germanium and Tin Compounds Containing a Bulky Diketiminato Ligand. Organometallics 20:1190-1194.

263. 2001 Eichler, B. E., L. Pu, M. Stender, and P. P. Power. The synthesis and structure of sterically encumbered terphenyl tin(II) halide derivatives: simultaneous existence of monomers and dimers in the crystalline phase. Polyhedron 20:551-556.

264. 2001 Stender, M., L. Pu and P. P. Power. Stabilized Terphenyl-Substituted Digermene Derivatives of Simple Organic Groups and Their Halide Precursors: Preference for Symmetrically Bonded Structures. Organometallics 20:1820-1824.

265. 2001 Hardman, N. J. and P. P. Power. Dimeric Gallium Oxide and Sulfide Species Stabilized by a Sterically Encumbered b-Diketiminate Ligand. Inorganic Chemistry 40:2474-2475.

266. 2001 Twamley, B., N. J. Hardman and P. P. Power. A primary monomeric alane: [N, N'-bis(2,6-diisopropylphenyl)pentane-2,4-diiminato-N,N’]dihydroaluminum. Acta Crystallographica Section E E57:m227-m228.

267. 2001 Stender, M., B. E. Eichler, N. J. Hardman, P. P. Power, J. Prust, M. Noltemeyer, and H. W. Roesky. Synthesis and Characterization of HC{C(Me)N(C6H3-2,6-i-Pr2)}2MX2 (M = Al, X = Cl, I; M = Ga, In, X = Me, Cl, I): Sterically Encumbered b-Diketiminate Group 13 Metal Derivatives. Inorganic Chemistry 40:2794-2799.

268. 2001 Hardman, N. J., C. Cui, H. W. Roesky, W. H. Fink, and P. P. Power. Stable, Monomeric Imides of Aluminum and Gallium: Synthesis and Characterization of [{HC(MeCDippN)2}MN-2,6-Trip2C6H3] (M = Al or Ga; Dipp = 2,6-iPr2C6H3; Trip = 2,4,6-iPr3C6H2). Angewandte Chemie International Edition 40:2172-2174.

269. 2001 Hardman, N. J. and P. P. Power. Unique structural isomerism involving tetrazole and amide/azide derivatives of gallium. Journal of the Chemical Society, Chemical Communications, 1184-1185.

270. 2001 Hinchley, S. L., C. A. Morrison, D. W. H. Rankin, C. L. B. Macdonald, R. J. Wiacek, A. Voigt, A. H. Cowley, M. F. Lappert, G. Gundensen, J. A. C. Clyburne, and P. P. Power. Spontaneous Generation of Stable Pnictinyl Radicals from “Jack-in-the-Box” Dipnictines: A Solid-State, Gas-Phase, and Theoretical Investigation of the Origins of Steric Stabilization. Journal of the American Chemical Society 123:9045-9053.

271. 2001 Hardman, N. J., P. P. Power, J. D. Gorden, C. L. B. Macdonald, and A. H. Cowley. Gallium-boron donor-acceptor bonds. Journal of the Chemical Society, Chemical Communications, 1866-1867.

272. 2001 Stender, M., A. D. Phillips and P. P. Power. Characterization and Bonding of the Cation [Ge{N(C6H3-2,6-i-Pr2)CMe}2CH]+: Comparison with the Isoelectronic Ga{N(C6H3-2,6-i-Pr2)CMe}2CH. Inorganic Chemistry 40:5314-5315.

273. 2001 Setaka, W., K. Sakamoto, M. Kira, and P. P. Power. Synthesis and Structure of Stable Tri-tert-butylgermyl-Substituted Stannylene and Germylene. Organometallics 20:4460-4462.

274. 2001 Pu, L., N. J. Hardman and P. P. Power. Attempted Isolation of Heavier Group 14 Element Ketone Analogues: Effect of O–H···p-Ar Hydrogen Bonding on Geometry. Organometallics 20:5105-5109. (In Press #3 at last review.)

275. 2001 Stender, M., R. J. Wright, B. E. Eichler, J. Prust, M. M. Olmstead, H. W. Roesky, and P. P. Power. The synthesis and structure of lithium derivatives of the sterically encumbered b-diketiminate ligand [{(2,6-Pri2H3C6)N(CH3)C}2CH]–, and a modified synthesis of the aminoimine precursor. Journal of the Chemical Society, Dalton Transactions, 3465-3469. (In Press #1 at last review.)

276. 2002 Burford, N., P. J. Ragogna, K. N. Robertson, T. S. Cameron, N. J. Hardman, and P. P. Power. Coordination Chemistry Umpolung: A Gallane Ligand on a Phosphine Lewis Acceptor. Journal of the American Chemical Society 124:382-383.

277. 2002 Baldwin, R. K., K. A. Pettigrew, J. C. Garno, P. P. Power, G.-Y. Liu, and S. M. Kauzlarich. Room Temperature Solution Synthesis of Alkyl-Capped Tetrahedral Shaped Silicon Nanocrystals. Journal of the American Chemical Society 124:1150-1151.

278. 2002 Hardman, N. J., B. Twamley, M. Stender, R. Baldwin, S. Hino, B. Schiemenz, S. M. Kauzlarich, and P. P. Power. Unusual structures of lithium terphenyl derivatives. Journal of Organometallic Chemistry 643-644:461-467.

279. 2002 Stender, M. and P. P. Power. Reaction of {HC(CMeNAr)2}Li (Ar = 2,6-i-Pr2C6H3) with indium monochloride to yield the In–In bonded dimer [{HC(CMeNAr)2}InCl]2 and the hydroxide [{HC(CMeNAr)2}InCl(m-OH)]2. Polyhedron 21:525-529.

280. 2002 Sanakis, Y., P. P. Power, A. Stubna, and E. Münck. Mössbauer Study of the Three-Coordinate Planar FeII Thiolate Complex [Fe(SR)3]– (R = C6H2-2,4,6-tBu3): Model for the Trigonal Iron Sites of the MoFe7S9:Homocitrate Cofactor of Nitrogenase. Inorganic Chemistry 41:2690-2696.

281. 2002 Stender, M., A. D. Phillips, R. J. Wright, and P. P. Power. Synthesis and Characterization of a Digermanium Analogue of an Alkyne. Angewandte Chemie International Edition 41:1785-1787.

282. 2002 Phillips, A. D., R. J. Wright, M. M. Olmstead, and P. P. Power. Synthesis and Characterization of 2,6-Dipp2-H3C6SnSnC6H3-2,6-Dipp2 (Dipp = C6H3-2,6-Pri2): A Tin Analogue of an Alkyne. Journal of the American Chemical Society 124:5930-5931.

283. 2002 Stender, M., A. D. Phillips and P. P. Power. Formation of (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) via reaction of Ar*GeGeAr* with 2,3-dimethyl-1,3-butadiene: evidence for the existence of a germanium analogue of an alkyne. Journal of the Chemical Society, Chemical Communications, 1312-1313.

284. 2002 Leppert, V. J., A. K. Murali, S. H. Risbud, M. Stender, P. P. Power, C. Nelson, P. Banerjee, and A. Mayes. High-resolution electron microscopy and microanalysis of ordered arrays of size-controlled amorphous gallium nitride nanoparticles synthesized in situ in a block copolymer matrix. Philosophical Magazine B 82:1047-1054.

285. 2002 Panda, A., M. Stender, R. J. Wright, M. M. Olmstead, P. Klavins, and P. P. Power. Synthesis and Characterization of Three-Coordinate and Related b-Diketiminate Derivatives of Manganese, Iron and Cobalt. Inorganic Chemistry 41:3909-3916.

286. 2002 Hardman, N. J, A. D. Phillips and P. P. Power. "Bonding and Reactivity of a b-Diketiminate, Gallium(I), Carbene Analogue." The Chemistry of Group 13 Metal Carbene Analogues. ACS Symposium Series 822, Chapter 1, 2-15. (In Press #2 at last review.)

287. 2002 Wright, R. J., A. D. Phillips, N. J. Hardman, and P. P. Power. The “Diindene” ArInInAr (Ar = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-Pri2). Dimeric versus Monomeric In(I) Aryls: para-Substituent Effects in Terphenyl Ligands. Journal of the American Chemical Society 124:8538-8539.

288. 2002 Hardman, N. J., R. J. Wright, A. D. Phillips, and P. P. Power. Synthesis and Characterization of the Neutral “Digallene” Ar'GaGaAr' and Its Reduction to Na2Ar'GaGaAr' (Ar' = 2,6-Dipp2C6H3, Dipp = 2,6-iPr2C6H3). Angewandte Chemie International Edition 41:2842-2844.

289. 2002 Power, P. P. "Multiple Bonding Between Heavier Group 13 Elements." Structure and Bonding. Volume 103: Group 13 Elements-Research Trends - Book 1. Editors: Atwood/Roesky. Springer-Verlag, Berlin Heidelberg, pp. 57-84.

290. 2002 Dorn, H., H. W. Roesky, and P. P. Power. RSi(OH)3 and RSi(NH2)3 [R = 2,6-iPr2C6H3N(SiMe3)]: Synthesis of Stable Organosilanes with Three Functional Groups. Inorganic Syntheses 33:230-233.

291. 2002 Eichler, B. E., A. D. Phillips, S. T. Haubrich, B. V. Mork, and P. P. Power. Synthesis, Structures and Spectroscopy of the Metallostannylenes

(h5-C5H5)(CO)3M––C6H3-2,6-Ar2 (M = Cr, Mo or W; Ar = C6H2-2,4,6-Me3, C6H2-2,4,6-Pri3). Organometallics 21:5622-5627.

292. 2002 Phillips, A. D. and P. P. Power. Models for Bonding in the Alkali Metal-Gallium Clusters K2Ga4(C6H3-2,6-Trip2)2 and Na2Ga4Trip6 (Trip = C6H2-2,4,6-i-Pr3): Importance of Alkali Metal-Aryl Interactions. Journal of Cluster Science 13:569-586.

293. 2003 Panda, A., M. Stender, M. M. Olmstead, P. Klavins, and P. P. Power. Reactions of M{N(SiMe3)2}2 (M = Mn, Fe or Co) with pyridine and 4,4'-bipyridyl: structural and magnetic studies. Polyhedron 22:67-73.

294. 2003 Shah, S., B. E. Eichler, R. C. Smith, P. P. Power, and J. D. Protasiewicz. Synthesis and solid state structures of increasingly sterically crowded 1,4-diiodo-2,3,5,6-tetraarylbenzenes: a new series of bulky benzenes and aryls. New Journal of Chemistry 27:442-445.

295. 2003 Wright, R. J., A. D. Phillips, T. L. Allen, W. H. Fink, and P. P. Power. Synthesis and Characterization of the Monomeric Imides of Ar'MNAr'' (M = Ga or In; Ar' or Ar'' = Terphenyl Ligands) with Two-Coordinate Gallium and Indium. Journal of the American Chemical Society 125:1694-1695.

296. 2003 Power, P. P. Persistent and Stable Radicals of the Heavier Main Group Elements and Related Species. Chemical Reviews 103:789-809.

297. 2003 Hardman, N. J., R. J. Wright, A. D. Phillips, and P. P. Power. Structures, Bonding, and Reaction Chemistry of the Neutral Organogallium(I) Compounds (GaAr)n (n = 1 or 2) (Ar = Terphenyl or Related Ligand): An Experimental Investigation of Ga–Ga Multiple Bonding. Journal of the American Chemical Society 125:2667-2679.

298. 2003 Richards, A. F., A. D. Phillips, M. M. Olmstead, and P. P. Power. Isomeric Forms of Divalent Heavier Group 14 Element Hydrides: Characterization of Ar´(H)GeGe(H)Ar´ and Ar´H2GeGeAr´·PMe3 (Ar´ = C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2). Journal of the American Chemical Society 125:3204-3205.

299. 2003 Pettigrew, K. A., P. P. Power and S. M. Kauzlarich. "A New Synthetic Route to Alkyl Terminated Silicon Nanoparticles." Materials Research Society Symposium Proceedings, Vol. 737, Symposium F: Nanocrystalline Semiconductor Materials and Devices, F1.8.1-F1.8.6.

300. 2003 Phillips, A. D., S. Hino and P. P. Power. A Reversible Valence Equilibrium in a Main Group Compound. Journal of the American Chemical Society 125:7520-7521.

301. 2003 Power, P. P. Silicon, germanium, tin and lead analogues of acetylenes. Journal of the Chemical Society, Chemical Communications, 2091-2101.

302. 2003 Hwang, C.-S. and P. P. Power. Synthesis and Characterization of (THF)3Li(NC)Cu(C6H3-2,6-Mes2) and Br(THF)2Mg (C6H3-2,6-Trip2) (Mes = C6H2-2,4,6-Me3; Trip = C6H2-,2,4,6-i-Pr3): The Structures of a Monomeric Lower-Order Lithium Organocyanocuprate and a Bulky Terphenyl Grignard Reagent in the Solid State. Bulletin of the Korean Chemical Society 24:605-609.

303. 2003 Wright, R. J., A. D. Phillips and P. P. Power. The [2+4] Diels-Alder Cycloadditon Product of a Probable Dialuminene, Ar'AlAlAr' (Ar'= C6H3- 2,6-Dipp2; Dipp = C6H3-2,6-Pri2), with Toluene. Journal of the American Chemical Society 125:10784-19785.

304. 2003 Pu, L., A. D. Phillips, A. F. Richards, M. Stender, R. S. Simons, M. M. Olmstead, and P. P. Power. Germanium and Tin Analogues of Alkynes and Their Reduction Products. Journal of the American Chemical Society 125:11626-11636.

305. 2003 Richards, A. F., H. Hope and P. P. Power. Synthesis and Characterization of Neutral, Homo and Heteronuclear Clusters with Unsubstituted Germanium or Tin Atoms. Angewandte Chemie International Edition 42:4071-4074.

306. 2003 Stanciu, C., M. M. Olmstead, A. D. Phillips, M. Stender, and P. P. Power. Synthesis and Characterizations of the Very Bulky Phenols ArOH and Ar'OH (Ar = C6H3-2,6-Trip2, Trip = C6H2-2,4,6-iPr3; Ar' = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-iPr2) and Their Lithium and Sodium Derivatives (LiOAr')2 and (NaOAr*)2. European Journal of Inorganic Chemistry 3495-3500.

307. 2003 Pettigrew, K. A.; Q. Liu, P. P. Power, and S. M. Kauzlarich. Solution Synthesis of Alkyl- and Alkyl/Alkoxy-Capped Silicon Nanoparticles via Oxidation of Mg2Si. Chemistry of Materials 15:4005-4011.

308. 2003 Eichler, B. E., A. D. Phillips and P. P. Power. Reaction of Phenyllithium with the Stannylene Ar*SnPh (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-Pri3) and the Distannylstannylene Sn(SnPh2Ar*)2. Organometallics 22:5423-5426.

309. 2004 Wiberg, N. and P. P. Power. Book chapter entitled "Molecular Cages and Clusters of the Heavier Group 14 Elements (E = Si, Ge, Sn or Pb) of Formula EnRm (n > m)" in “Molecular Clusters of the Main Group Elements” Ed. Driess, M., H. Nöth, Wiley-VCH, Chapter 2.5, 188-208.

310. 2004 Stanciu, C., A. F. Richards and P. P. Power. Characterization of (Ar' = C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2): A Stable Structural Analogue for a Heavier Group 14 Element Monobridged Alkene Isomer (M = Sn or Pb). Journal of the American Chemical Society, 126, 4106-4107.

311. 2004 Hino, S., M. Brynda, A. D. Phillips, and P. P. Power. Synthesis and Characterization of a Quasi-One-Coordinate Lead Cation. Angewandte Chemie International Edition 43, 2655-2658.

312. 2004 Cui, C., M. M. Olmstead, and P. P. Power. Reactivity of Ar'GeGeAr' (Ar' = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-iPr2) toward Alkynes: Isolation of a Stable Digermacyclobutadiene. Journal of the American Chemical Society 126, 5062-5063.

313. 2004 Cui, C., M. Brynda, M. M. Olmstead, and P. P. Power. Synthesis and Characterization of the Non-Kekulé, Singlet Biradicaloid Ar¢Ge(m-NSiMe3)2GeAr¢ (Ar¢ = 2,6-Dipp2C6H3, Dipp = 2,6-i-Pr2C6H3). Journal of the American Chemical Society 126, 6510-6511.

314. 2004 Richards, A. F., M. Brynda, M. M. Olmstead, and P. P. Power. Characterization of Ge5R4 (R = CH(SiMe3)2, C6H3-2,6-Mes2): Germanium Clusters of a New Structural Type with Singlet Biradical Character. Organometallics, 23, 2841-2844.

315. 2004 Richards, A. F., M. Brynda, and P. P. Power. Effects of the Alkali Metal Counter Ions on the Germanium-Germanium Double Bond Length in a Heavier Group 14 Element Ethenide Salt. Chemical Communications, 1592-1593.

316. 2004 Richards, A.F., , M. Brynda, and P. P. Power. Synthesis and Characterization of Ge₂{Sn(X)Ar^#}₃ and Ga₂{Ge(X)Ar^#}₃ (Ar^# = C₆H₃-2,6-Mes₂), X = (C1/I): Rare Examples of Mixed Heavier Group 14/14, 13/14 Element Clusters. Organometallics 23, 4009-4011.

317. 2004 Zhu, Hongping, J. Chai, V. Chandrasekhar, H.W. Roesky, J. Magull, D. Vidovic, H. Schmidt, M. Noltemeyer, P.P. Power, and W.A. Merrill. Two Tyeps of Intramolecular Addition of an Al-N Multiple-Bonded Monomer LAINAr' Arising from the Reaction of LAI with N₃Ar' (L = HC[(CMe)(NAr)]₂, Ar' = 2,6-Ar₂C₆H₃, Ar = 2,6-iPr₂C₆H₃). Journal of the American Chemical Society 126, 9472-9473.

318. 2004 Richards, Anne F., M. Brynda, P.P. Power. Reduction of Digermenes with Alkali Metals: Salts of Formula M₂[{Ge(H)Ar'}₂] (M = Li, Na or K, Ar' = Terphenyl) with Three Different Structures. Journal of the American Chemical Society 126, 10530-10531.

319. 2004 Power, P. P. Some Highlights from the Development and Use of Bulky Monodentate Ligands. Journal of Organometallic Chemistry 689, 3904-3919.

320. 2004 Hino, S., Olmstead, M. M., Phillips, A.D., Wright, R.J., Power, P.P., Terphenyl Ligand Stabilized Lead(II) Derivatives: Steric Effects and Lead-Lead Bonding in Diplumbenes. Inorganic Chemistry 43, 7346-7352.

321. 2004 Wright, R.J., Power, P.P., Scott, B.L., Kiplinger, J.L., Uncommon h³=(N,C,C')-1-Azaallyl Bonding Mode for the Nacnac Ligand: A Bis(b-diketiminato)uranium(III) Iodide Complex. Organometallics 21, 4801-4803.

322. 2005 Munoz-Hernandez, Miguel-Angel; Montiel-Palma, Virginia; Huitron-Rattinger, Estefania; Cortes-Llamas, Sara; Tiempos-Flores, Norma; Grevy, Jean-Michel; Silvestru, Cristian; Power, P. P., Dichloro and Alkylchloro Gallium Derivatives of Dichalcogenoimidodiphosphinate ligands: Isolation of a Spirogallium Cation. Dalton Transactions, 193-199.

323. 2005 Hino, S., Olmstead, M. M., Fettinger, J.C., Power, P. P. Synthesis and Structure of Two Lithium Terphenyls and a “Halide Rich” Terphenyl Lithium Species. Journal of Organometallic Chemistry 690, 1638-1644.

324. 2005 Wright, R. J., Phillips, A. D., Hino, S. S., Power, P. P. Synthesis and Reactivity of Dimeric Ar'TlTlAr' and Trimeric (Ar''Tl)₃ (Ar', Ar'' = Bulky Terphenyl Group) Thallium(I) Derivatives: Tl(I)-Tl(I) Bonding in Species Ligated by Monodentate Ligands. Journal of the American Chemical Society 127, 4794-4799.

325. 2005 Stanciu, C., Hino, S., Stender, M., Richards, A. F., Olmstead, M. M., Power, P. P. Synthesis and Characterization of Ge(II), Sn(II) and Pb(II) Monoamides With –NH₂ Ligands. Inorganic Chemistry 44, 2774-2780.

326. 2005 Razus, A.C., Nitu, C., Pavel, C., Ciuculescu, L-A., Cimpeanu, V., Stancui, C., Power, P.P. Oxidation of 1-(4'-substituted phenyl)-2-(4-methylphenyl)diazene – Benzylic substitution vs. C-azo bond breaking. Canadian Journal of Chemistry 83, 244-250.

327. 2005 Power, P.P. Synthesis and Some Reactivity Studies of Germanium, Tin and Lead Analogues of Alkynes. Applied Organometalic Chemistry, 19, 488-493.

328. 2005 Wright, R. J., Marcin Brynda, Power, P. P. A Monomeric Thallium(I) Amide in the Solid State: Synthesis and Structure of TIN(Me)Ar^Mes2 (Ar^Mes2 = C₆H₃-2,6-Mes₂). Inorganic Chemistry 44, 3368-3370.

329. 2005 Richards, A.F., Eichler, B. E., Brynda, M., Olmstead, M. M., Power, P. P. Metal-Rich, Neutral Cationic Organotin Clusters. Angewandte Chemie International Edition, Engl, 44, 2546-2549.

330. 2005 Phillips, A.D. Power, P.P., A main-group donor-acceptor adduct: 1,2,4,5-tetramethylimidazol-2-ylidene-tris(pentafluorophenyl)borane. Acta Crystallographica, C61, o291-o293.

331. 2005 Carter, R.S., Harley, S.J., Power, P.P., Augustine, M.P., Use of NMR Spectroscopy in the Synthesis and characterization of Air- and Water-stable silicon nanoparticles from Porous Silicon. Chemistry of Materials, 17, 2932-2939.

332. 2005 Nguyen, T., Panda, A., Olmstead, M. M., Richards, A. F., Stender, M., Brynda, M., Power, P. P. Synthesis and Characterization of Quasi-Two-Coordinate Transition Metal Dithiolates M(SAr*)₂ (M = Cr, Mn, Fe, Co, Ni, Zn; Ar* = C₆H₃-2,6(C₆H₂-2,4,6-Prⁱ₃)₂. Journal of the American Chemical Society 127, 8545-8552.

333. 2005 Koetzle, T.F., Schultz, A.J., Henning, R., Albinati, A., Klooster, W.T., Eichler, B.E., Power, P.P., Neutron Diffraction Analysis of the first stable Hydride Derivatives of a Divalent Group 14 Metal. Comptes Rendu, 8, 1487-1490.

334. 2005 Zhu, H., Chai, J., Jancik, V., Roesky, H.W., Merrill, W.A., Power, P.P., The Selective Preparation of an Aluminum Oxide and its Isomeric C-H Activated Hydroxide. Journal of the American Chemical Society 127, 10170-10171.

335. 2005 Zhu, H., Chai, J., Fan, H., Roesky, H.W., He, C., Jancik, V., Schmidt, H-G., Noltemeyer, M., Merrill, W.A., Power, P.P., A Stable Aluminacyclopropene LAl(h²-C₂H₂) and its End-On Azide Insertion to an Aluminaazacyclobutene, Angewandte Chemie International Edition 44, 5090-5093.

336. 2005 Spikes, G.H., Fettinger, J.C., Power, P.P., Facile Activation of Dihydrogen by an Unsaturated Heavier Main Group Compound, Journal of the American Chemistry Society 127, 12232-12233.

337. 2005 Nguyen, T., Sutton, A.D., Brynda, M., Fettinger, J.C., Long, G.J., Power, P.P., Synthesis of a Stable Compound with Five-Fold Bonding Between Two Chromium (I) Centers. Science, 310, 844-847.

338. 2005 Hino, S., Olmstead, M.M., Power, P.P., Characterization of a Plumbylplumbylene: An Isomeric Form of a Diplumbene. Organometallics, 23, 5484-5486.

339. 2005 Power, P.P., Stanciu, C., Nowik, I., Herber, R., Bonding and Metal-Atom Dynamics in Two Unique Sn(I)-Sn(III) Complexes. Inorganic Chemistry 44, 9461-9463.

340. 2005 Fox, A.R., Wright, R.J., Rivard, E., Power, P.P., Tl₂[Aryl₂P₄]: A Thallium Complexed Diarytetraphosphabutadienediide and its Two-Electron Oxidation to a Diaryltetraphosphabicyclobutane, Aryl₂P₄ Angewandte Chemie International Edition 44, 7884-7887.

341. 2005 Cui, C., Olmstead, M.M., Fettinger, J.C., Spikes, G.H., Power, P.P., Reactions of the Heavier Group 14 Element Alkyne Analogues Ar'EEAr' (Ar' = C₆H₃-2,6(C₆H₃-2,6-Prⁱ₂)₂; E = Ge, Sn) with Unsaturated Molecules: Probing the Character of the EE Multiple Bonds. Journal of the American Chemical Society 127, 17530-17541.

342. 2005 Spikes, G.H. Peng, Y., Fettinger, J.C., Steiner, J., Power, P.P., Different Reactivity of the Heavier Group 14 Element alkyne Analogues Ar'MMAr' (M = Ge, Sn; Ar' = C₆H₃-2,6(C₆H₃-2,6-Prⁱ₂)₂) with R₂NO. Chemical Communications, 6041-6043.

343. 2006 Wright, R.J., Rivard, E., Power, P.P., Synthesis of the Sterically Encumbering Terphenyl Silyl and Alkyl Amines HN(R)Ar^Mes2 (R = Me or SiMe₃), their lithium derivatives LiN(R)Ar^Mes2, and the tertiary amine Me₂NAr^Mes2. Inorganica. Chim. Acta., 359, 1939-1946.

344. 2006 Power, P.P. Stable Derivatives of New Isomeric Forms of Heavier Group 14 Element Alkene Analogues. ACS Symposium Series, 917, 179-191.

345. 2006 Stanciu, C., Richards, A.F., Stender, M., Olmstead, M.M., Power, P.P., New Terphenylphenoxides of Group 13 and 14 Elements. Polyhedron, 25, 477-483.

346. 2006 Spikes, G.H., Peng, Y., Fettinger, J.C., Power, P.P.; Synthesis and Characterization of the Monomeric Sterically Encumbered Diaryls E{C₆H₃-2,6-Prⁱ₂)₂}₂ (M = Ge, Sn, or Pb). Zeitschrift fur Anorganische und Allgemeine Chemie, 632, 1005-1010.

347. 2006 Stanciu, C., Richards, A.F., Fettinger, J.C., Brynda, M., Power, P.P.; Synthesis and characterization of New, Modified Terphenyl Ligands: Increasing the Rotational Barrier for Flanking Rings. Journal of Organometallic Chemistry 691, 2540-2545.

348. 2006 Stanciu, C., Fox, A.R. Richards, A.F., Fettinger, J.C., Power, P.P.; ipso-and para-functionalization of metal-Terphenyl Ligands with Substituted Methyl Groups: Unusual Head to Tail Coupling of Terphenyl Moieties. Journal of Organometallic Chemistry, 691, 2546-2553.

349. 2006 Brynda, M., Gagliardi, L., Widmark, P., Power, P.P., Roos, B.; A Quantum Chemical Study of the Quintiple Bond Between Two Chromium Centers in [PhCrCrPh]: trans-Bent versus Linear Geometry. Angewandte Chemie International Edition 45, 3804 – 3807.

350. 2006 Jung, Y; Brynda, M.; Power, P.P.; Head-Gordon, M. Ab Initio Quantum Chemistry Calculations on the Electronic Structure of Heavier Alkyne Congeners: Diradical Character and Reactivity. Journal of the American Chemical Society, 128, 7185-7192.

351. 2006 Herber, R., Hitchcock, P.B., Lappert, M.F., Nowik, I., Power, P.P.; Highter Nuclearity Group 14 Metalloid Clusters: [Sn₉{Sn(NRR')}₆] (R = C₆H₃iPr₂-2,6; R' = SiMe₃ or SiMe₂Ph. Angewandte Chemie International Edition 45, 4333-4337.

352. 2006 Fischer, R. C.; Pu, L.; Fettinger, J. C.; Brynda, M. A., Power, P. P. Very Large Changes in Bond Length and Bond Angle in a Heavy Group 14 Element Alkyne Analogue by Modification of a Remote Ligand Substituent. Journal of the American Chemical Society, 128, 11366-11367.

353. 2006 Zhu, Z., Wright, R. J., Olmstead, M. M., Rivard, E., Brynda, M., Power, P. P. Zinc-Zinc Bonded Compound and its Derivatives Bridged by One or Two Hydrogen Atoms: A New Type of Zn-Zn Bonding. Angewandte Chemie International Edition, 45, 5807-5810.

354. 2006 Wright, R. J., Fettinger, J. C., Power, P. P. Synthesis and Structure of the "Dialuminyne" Na₂Ar'AlAlAr' and Na₂(Ar"Al)₃ (Ar' = C₆H₃-2,6-(C₆H₃-2,6-Prⁱ₂)₂ Ar" = C₆H₃-2,6-(C₆H₂-2,4,6-Me₃)₂: Al-Al Bonding in Al₂Na₂ and Al₃Na₂ and Clusters. Angewandte Chemie International Edition, 45, 5953-5956.

355. 2006 Rivard, E., Merrill, W. A., Fettinger, J. C., Power, P. P. A donor-stabilization strategy for the preparation of compounds featuring P=B and As=B double bonds. Chemical Communications, 3800-3802.

356. 2006 Wright, R. J., Brynda, M. Fettinger, J. C., Betzer, A. R., Power, P. P.; Quasi-Isomeric Gallium Amides and Imides GaNR₂ and RGaNR (R = organic group): Reactions of the Digallene, Ar'GaGaAr' (Ar' = C₆H₃-2,6-(C₆H₃-2,6-Prⁱ₂)₂ with Unsaturated Nitrogen Compounds. Journal of the American Chemical Society 128, 12498-12509.

357. 2006 Spikes, G. H., Giuliani, J. R., Augustine, M. P., Nowik, I. Herber, R. H., Power, P. P. Solid State ¹¹⁹Sn NMR and Mössbauer Spectroscopy of the "Distannynes": Evidence for Large Structural Differences in the Crystalline Phase Inorganic Chemistry 45, 9132-9136.

358. 2006 Zhongliang, Z., Fischer, R. C., Fettinger, J. C., Rivard, E., Brynda, M., Power, P. P. Synthesis, Structural Characterization and Spectroscopy of the Cadium-Cadium Bonded Molecular Species Ar'CdCdAr' (Ar' = C₆H₃-2,6Prⁱ₂)₂) Journal of the American Chemical Society 128, 15068-15069.

359. 2007 Spikes, G. H., Power, P. P. Lewis Base Induced Tuning of the Ge-Ge Bond Order in a "Digermyne". Chemical Communications, 85-87.

360. 2007 Pickering, A. L., Mitterbauer, C., Browning, N. D., Kauzlarich, S. M., Philip, P. P. Room Temperature Synthesis of Surface-Functionalised Boron Nanoparticles. Chemical Communications, 580-582.

361. 2007 Rivard, E., Sutton, A.D., Fettinger, J.C. Power, P.P.; Synthesis of the sterically congested diarylphosphines Ar^Trip2P(Ph)H (Ar^Trip2 = C₆H₃-2,6(C₆H₂-2,4,6-Prⁱ₃)) and Ar^Mes2 = C₆H₃-2,6(C₆H₂_2,4,6-Me₃)) and the monomeric Sn(II)-diphosphide [Ar^Mes2P(Ph)]₂Sn. Inorganic Chimica Acta 360, 1278-1286.

362. 2007 Rivard, E., Merrill, A., Fettinger, J. C., Wolf, R., Spikes, G. H., Power, P. P. Boron-Pnictogen Multiple Bonds: Donor-stabilized P=B and As=B Double Bonds and a Hindered Iminoborane with a B-N Triple Bond. Inorganic Chemistry 46, 2971-2978.